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In this work we include electron-electron interaction beyond Hartree-Fock level in our non-equilibrium Green's function approach by a crude form of GW through the Single Plasmon Pole Approximation. This is achieved by treating all…

Mesoscale and Nanoscale Physics · Physics 2016-05-02 David O. Winge , Martin Franckié , Claudio Verdozzi , Andreas Wacker , Mauro F. Pereira

A prototypical model of a one-dimensional metallic monatomic solid containing noninteracting electrons is studied, where the argument of the cosine potential energy periodic with the lattice contains the first reciprocal lattice vector G1 =…

Mesoscale and Nanoscale Physics · Physics 2020-11-20 David C. Johnston

We propose a range-separated hybrid exchange-correlation functional to calculate solid-state material properties. The functional mixes Hartree-Fock exchange with the semilocal exchange of the meta-generalized gradient approximation…

Materials Science · Physics 2025-02-27 Subrata Jana , Abhishek Bhattacharjee , Suman Mahakal , Szymon Smiga , Prasanjit Samal

In this article, we discuss how a kind of hybrid computation, which employs symbolic, numeric, classic, and quantum algorithms, allows us to conduct Hartree-Fock electronic structure computation of molecules. In the proposed algorithm, we…

Quantum Physics · Physics 2024-06-19 Ichio Kikuchi , Akihito Kikuchi

The Hartree-Fock exchange potential is fundamental for capturing quantum mechanical exchange effects but faces critical challenges in large-scale applications due to its nonlocal and computationally intensive nature. This study introduces a…

Chemical Physics · Physics 2025-09-03 Fei Xu

As nuclear wave functions have to obey the Pauli principle, potentials issued from reaction theory or Hartree-Fock formalism using finite-range interactions contain a non-local part. Written in coordinate space representation, the…

Nuclear Theory · Physics 2010-01-06 N. Michel

Exact (Hartree Fock) exchange is needed to overcome some of the limitations of local and semilocal approximations of density functional theory (DFT). So far, however, computational cost has limited the use of exact exchange in plane wave…

Strongly Correlated Electrons · Physics 2009-11-13 Xifan Wu , Annabella Selloni , Roberto Car

The crystalline structure of ground-state orthorhombic SrRuO$_3$ is reproduced by applying hybrid density functional theory scheme to the functionals based on the revised generalized-gradient approximations for solid-state calculations. The…

Materials Science · Physics 2016-10-11 Š. Masys , V. Jonauskas

We review two common numerical schemes for Coulomb potential evaluation that differ only in their radial part of the solutions in the spherical harmonic expansion (SHE). One is based on finite-difference method (FDM) while the other is…

Chemical Physics · Physics 2022-05-25 Po-Hao Chang , Zachary Buschmann , Rajendra R. Zope

In the context of the development of NMR Fermi contact shift calculations for assisting structural characterization of battery materials, we propose an accurate, efficient, and robust approach based on the use of an all electron method. The…

Materials Science · Physics 2012-04-06 Yuesheng Zhang , Aurore Castets , Dany Carlier , Michel Ménétrier , Florent Boucher

We report Hartree-Fock (HF) based pseudopotentials suitable for plane-wave calculations. Unlike typical effective core potentials, the present pseudopotentials are finite at the origin and exhibit rapid convergence in a plane-wave basis;…

Materials Science · Physics 2008-02-28 W. A. Al-Saidi , E. J. Walter , A. M. Rappe

Using the newly developed VASP2WANNIER90 interface we have constructed maximally localized Wannier functions (MLWFs) for the e_g states of the prototypical Jahn-Teller magnetic perovskite LaMnO3 at different levels of approximation for the…

Strongly Correlated Electrons · Physics 2015-06-03 C. Franchini , R. Kovacik , M. Marsman , S. Sathyanarayana Murthy , J. He , C. Ederer , G. Kresse

Hybrid functionals, which mix a fraction of Hartree-Fock (HF) exchange with local or semilocal exchange, have become increasingly popular in quantum chemistry and computational materials science. Here, we assess the accuracy of the…

Materials Science · Physics 2018-10-19 Mauricio A. Flores , Walter Orellana , Eduardo Menéndez-Proupin

Improving electronic structure calculations for practical and technologically-important materials has been a never-ending pursue. This is especially true for transition and post-transition metal oxides for which the current first-principles…

Materials Science · Physics 2019-10-23 Hengxin Tan , Haitao Liu , Yuanchang Li , Wenhui Duan , Shengbai Zhang

We present a self-consistent analytic theory of the intra-layer and inter-layer pair correlation functions in electron-electron and electron-hole fluid bilayer systems. Our approach involves the solution of a zero-energy scattering…

Mesoscale and Nanoscale Physics · Physics 2011-11-09 S. H. Abedinpour , R. Asgari , M. Polini , M. P. Tosi

We propose a short- and long-range corrected (SLC) hybrid scheme employing 100% Hartree-Fock (HF) exchange at both zero and infinite interelectronic distances, wherein three SLC hybrid density functionals with the D3 dispersion corrections…

Chemical Physics · Physics 2016-11-23 Chih-Wei Wang , Kerwin Hui , Jeng-Da Chai

The expensive cost of computing exact exchange in periodic systems limits the application range of density functional theory with hybrid functionals. To reduce the computational cost of exact change, we present a range-separated algorithm…

Chemical Physics · Physics 2023-07-26 Qiming Sun

By carefully choosing parameters and including more semi-core orbitals as valence electrons, we have constructed a high quality projected augmented wave (PAW) dataset that yields results comparable to existing full-potential linearized…

Strongly Correlated Electrons · Physics 2010-12-30 Chao Cao , Yu-ning Wu , Rashid Hamdan , Yun-Peng Wang , Hai-Ping Cheng

We report the compositional dependence of the electronic band structure for a range of III-V alloys. Density functional theory with the PBE functional is insufficient to mimic the electronic gap energies at different symmetry points of the…

Materials Science · Physics 2015-05-19 Jeremy W. Nicklas , John W. Wilkins

The construction of meta generalized gradient approximations based on the density matrix expansion (DME) is considered as one of the most accurate technique to design semilocal exchange energy functionals in two-dimensional density…

Materials Science · Physics 2018-05-09 Abhilash Patra , Subrata Jana , Prasanjit Samal
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