English
Related papers

Related papers: Hybrid functionals within the all-electron FLAPW m…

200 papers

Separating the Coulomb potential into short-range and long-range components enables the use of different electron repulsion integral algorithms for each component. The short-range part can be efficiently computed using the analytical…

Chemical Physics · Physics 2023-09-27 Qiming Sun

A first-principles computational method with self-consistent on-site and inter-site Hubbard functionals is able to treat local and non-local Coulomb interactions on an equal footing. To apply the method to understand solids with strong…

Materials Science · Physics 2024-10-17 Wooil Yang , Young-Woo Son

Using a linear combination of atomic orbitals approach, we report a systematic comparison of various Density Functional Theory (DFT) and hybrid exchange-correlation functionals for the prediction of the electronic and structural properties…

Materials Science · Physics 2008-05-07 D. I. Bilc , R. Orlando , R. Shaltaf , G. -M. Rignanese , Jorge Íñiguez , Ph. Ghosez

The high cost associated with the evaluation of Hartree-Fock exchange (HFX) makes hybrid functionals computationally challenging for large systems. In this work, we present an efficient way to accelerate HFX calculations with numerical…

Computational Physics · Physics 2020-09-09 Xinming Qin , Jie Liu , Wei Hu , Jinlong Yang

We propose a nonlocal theory of single-particle excitations. It is based on an off-diagonal effective medium and the projection operator method for treating the retarded Green function. The theory determines the nonlocal effective medium…

Strongly Correlated Electrons · Physics 2015-05-14 Y. Kakehashi , T. Nakamura , P. Fulde

EPW is an open-source software for $\textit{ab initio}$ calculations of electron-phonon interactions and related materials properties. The code combines density functional perturbation theory and maximally-localized Wannier functions to…

We examine the performance of our recently developed LFAs-PBE exchange-correlation (XC) potential [C.-R. Pan, P.-T. Fang, and J.-D. Chai, Phys. Rev. A, 2013, 87, 052510] for the high-order harmonic generation (HHG) spectra and related…

Chemical Physics · Physics 2016-06-14 Hsiao-Ling Sun , Wei-Tao Peng , Jeng-Da Chai

The Hartree-Fock exchange operator is an integral operator arising in the Hartree-Fock method and replaced by a multiplicative operator (a local potential) in Kohn-Sham density functional theory. This article presents a detailed analysis of…

We have investigated the electronic structure of fluorite Cu$_{2}$Se using density functional theory calculations within the LDA, PBE and AM05 approximations as well as with the non-local hybrid PBE0 and HSE approximations. Our results show…

Materials Science · Physics 2013-03-04 Mikael Råsander , Lars Bergqvist , Anna Delin

We lay out the extension of range-separated density-functional theory to a four-component relativistic frame-work using a Dirac-Coulomb-Breit Hamiltonian in the no-pair approximation. This formalism combines a wave-function method for the…

Chemical Physics · Physics 2018-12-12 Julien Paquier , Julien Toulouse

A self-consistent scheme for determining the optimal fraction of exact exchange for full-range hybrid functionals is presented and applied to the calculation of band gaps and dielectric constants of solids. The exchange-correlation…

Materials Science · Physics 2015-01-15 Jonathan H Skone , Marco Govoni , Giulia Galli

We present an efficient algorithm for computing the exact exchange contributions in the Hartree-Fock and hybrid density functional theory models on the basis of the fast multipole method (FMM). Our algorithm is based on the observation that…

Chemical Physics · Physics 2018-01-30 Hai-Anh Le , Toru Shiozaki

We describe an all-electron implementation of the Bethe-Salpeter equation (BSE) for the calculation of optical absorption spectra in the full-potential linearized augmented-plane-wave (FLAPW) method. So far, FLAPW implementations have…

Materials Science · Physics 2026-03-27 Jörn Stöhler , Stefan Blügel , Christoph Friedrich

Exchange hole is the principle constituent in density functional theory, which can be used to accurately design exchange energy functional and range separated hybrid functionals coupled with some appropriate correlation. Recently, density…

Materials Science · Physics 2017-09-14 Bikash Patra , Subrata Jana , Prasanjit Samal

In this paper we assess the predictive power of the self-consistent hybrid functional scPBE0 in calculating the band gap of oxide semiconductors. The computational procedure is based on the self-consistent evaluation of the mixing parameter…

Materials Science · Physics 2017-11-22 Jiangang He , Cesare Franchini

The lithium manganese oxide spinel Li$_x$Mn$_2$O$_4$, with $0\leq x\leq 2$, is an important example for cathode materials in lithium ion batteries. However, an accurate description of Li$_x$Mn$_2$O$_4$ by first-principles methods like…

Materials Science · Physics 2020-05-20 Marco Eckhoff , Peter E. Blöchl , Jörg Behler

The Heyd-Scuseria-Ernzerhof (HSE) density functionals are popular for their ability to improve the accuracy of standard semilocal functionals such as Perdew-Burke-Ernzerhof (PBE), particularly for semiconductor band gaps. They also have a…

Materials Science · Physics 2025-10-07 Jonathan E. Moussa , Peter A. Schultz , James R. Chelikowsky

We present a robust strategy to numerically sample the Coulomb potential in reciprocal space for periodic Born-von Karman cells of general shape. Our approach tackles two common issues of plane-wave based implementations of Coulomb…

Computational Physics · Physics 2024-02-05 Tobias Schäfer , William Z. Van Benschoten , James J. Shepherd , Andreas Grüneis

We evaluate the accuracy of electron densities and quasiparticle energy gaps given by hybrid functionals by directly comparing these to the exact quantities obtained from solving the many-electron Schrodinger equation. We determine the…

Materials Science · Physics 2021-01-15 A. R. Elmaslmane , Jack Wetherell , M. J. P. Hodgson , K. P. McKenna , R. W. Godby

Boltzmann transport calculations based on band structures generated with density functional theory (DFT) are often used in the discovery and analysis of thermoelectric materials. In standard implementations, such calculations require dense…

Materials Science · Physics 2018-07-04 Kristian Berland , Clas Persson