Related papers: The chemistry of interstellar molecules containing…

Context: Molecular hydrogen (H2) is the most abundant molecule in the circumstellar (CS) environments of young stars, and is a key element in giant planet formation. The measurement of the H2 content provides the most direct probe of the…

We report an astronomical detection of HC$_4$NC for the first time in the interstellar medium with the Green Bank Telescope toward the TMC-1 molecular cloud with a minimum significance of $10.5 \sigma$. The total column density and…

In the interstellar medium of the Milky Way, certain elements -- e.g., Mg, Si, Al, Ca, Ti, Fe -- reside predominantly in interstellar dust grains. These grains absorb, scatter, and emit electromagnetic radiation, heat the interstellar…

We present chemical abundance analyses of sodium, iron-peak and neutron-capture elements for 97 kinematically selected thick disk, inner halo and outer halo stars with metallicities -3.3<[Fe/H]<-0.5. The main aim of this study is to examine…

We use ultraviolet spectra of Capella from the Hubble Space Telescope (HST) and Far Ultraviolet Spectroscopic Explorer (FUSE) satellites to study interstellar absorption lines from the Local Interstellar Cloud (LIC). Measurements of these…

We describe a moderate-resolution FUSE survey of H2 along 70 sight lines to the Small and Large Magellanic Clouds, using hot stars as background sources. FUSE spectra of 67% of observed Magellanic Cloud sources (52% of LMC and 92% of SMC)…

CF$^{+}$ has been established as a valuable diagnostic tool for investigating photo-dissociation regions (PDRs) and fluorine abundances in the Milky Way. However, its role in extragalactic environments remains largely uncharted. Our…

We discuss the abundances of interstellar CH, CH+, and CN in the Magellanic Clouds (MC), derived from spectra of 7 SMC and 13 LMC stars obtained (mostly) with the VLT/UVES. CH and/or CH+ are detected toward 3 SMC and 9 LMC stars; CN is…

In this paper we use a number of observations to construct an integrated picture of the ionisation in the interiors of quiescent warm opaque interstellar clouds and in the intercloud medium (ICM) outside dense HII regions and hot dilute…

Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…

We use 3-dimensional numerical simulations of self-gravitating compressible turbulent gas in combination with Lagrangian tracer particles to investigate the mixing process of molecular hydrogen (H2) in interstellar clouds. Tracer particles…

We describe a moderate-resolution FUSE mini-survey of H2 in the Milky Way and Magellanic Clouds, using four hot stars and four AGN as background sources. FUSE spectra of nearly every stellar and extragalactic source exhibit numerous…

We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several…

We present high-resolution (FWHM ~ 0.3-1.5 km/s) spectra of interstellar Ca I absorption toward 30 Galactic stars. Comparisons of the column densities of Ca I, Ca II, K I, and other species -- for individual components identified in the…

Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…

Context. The earliest phases of high-mass star formation are poorly understood. Aims. Our goal is to determine the physical conditions and kinematic structure of massive star-forming cloud clumps. Methods. We analyze H$_2$O 557 GHz line…

Using high resolution infrared spectroscopy we have surveyed twenty sightlines for H3+ absorption. H3+ is detected in eight diffuse cloud sightlines with column densities varying from 0.6x10^14 cm^-2 to 3.9x10^14 cm^-2. This brings to…

We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…

Measurements of molecular hydrogen (H_2) column densities are presented for the first six rotational levels (J=0 to 5) for 73 extragalactic targets observed with FUSE. All of these have a final signal-to-noise ratio larger than \snlimit,…

To study the usefulness of \CFP\ as a tracer of the regions where C\p\ and \HH\ coexist in the interstellar medium. We used the Plateau de Bure Interferometer to synthesize \CFP\ J=1-0 absorption at 102.6 GHz toward the core of the distant…