Related papers: The chemistry of interstellar molecules containing…
Diffuse interstellar clouds show large abundances of H_3^+ which can be maintained only by a high ionization rate of H_2. Cosmic rays are the dominant ionization mechanism in this environment, so the large ionization rate implies a high…
Context: Hydrides of the most abundant heavier elements are fundamental molecules in cosmic chemistry. Some of them trace gas irradiated by UV or X-rays. Aims: We explore the abundances of major hydrides in W3 IRS5, a prototypical region of…
The abundance of fluorine is determined from the (2-0) R9 2.3358 micron feature of the molecule HF for several dozen normal G and K stars in the Galactic thin disk from spectra obtained with the Phoenix IR spectrometer on the 2.1-m…
The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We…
(Abridged) We use a combination of high resolution N-body simulations and semi-analytic techniques to follow the formation, the evolution and the chemical enrichment of cluster galaxies in a Lambda-CDM Universe. We model the transport of…
The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral…
According to traditional gas-phase chemical models, O2 should be abundant in molecular clouds, but until recently, attempts to detect interstellar O2 line emission with ground- and space-based observatories have failed. Following the…
We consider the possibility that solid molecular hydrogen is present in interstellar space. If so cosmic-rays and energetic photons cause ionisation in the solid leading to the formation of H6+. This ion is not produced by gas-phase…
Astrochemical models of interstellar clouds, the sites of stars, and planet formation require information about spin-state chemistry to allow quantitative comparison with spectroscopic observations. In particular, it is important to know if…
We present an analysis of the Fe II, Ge II, Mg I, Mg II, S I, S II, Si II and Zn II interstellar lines for 63 stars. The column density of Mg II, S II, Si II and Zn II is well correlated with the distance. However, the column density --…
We study the Intra-Halo Stellar Component (IHSC) of Milky Way-mass systems up to galaxy clusters in the Horizon-AGN cosmological hydrodynamical simulation. We identify the IHSC using an improved phase-space galaxy finder algorithm which…
We report the detection of linear and cyclic isomers of C3H and C3H2 towards various starless cores and review the corresponding chemical pathways involving neutral (C3Hx with x=1,2) and ionic (C3Hx+ with x = 1,2,3) isomers. We highlight…
A simple analytic model is presented to predict the near-IR H2 fluorescent line intensities emitted by diffuse interstellar clouds with a Plummer density profile. It is applicable to sightlines where (1) the column densities of H and H2…
Context. The detection of NH2CH2CH2OH (ethanolamine) in molecular cloud G+0.693-0.027 adds an additional player to the prebiotic molecules discovered so far in the interstellar medium (ISM). As this molecule might be formed through…
The majority of hydrogen in the interstellar medium (ISM) is in atomic form. The transition from atoms to molecules and, in particular, the formation of the H$_2$ molecule, is a key step in cosmic structure formation en route to stars.…
Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…
Sulphur is one of the most abundant elements in the Universe. Surprisingly, sulphuretted molecules are not as abundant as expected in the interstellar medium, and the identity of the main sulphur reservoir is still an open question. Our…
Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$…
While recent studies of the solar-mass protostar IRAS16293-2422 have focused on its inner arcsecond, the wealth of Herschel/HIFI data has shown that the structure of the outer envelope and of the transition region to the more diffuse ISM is…
Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds, which are near the beginning of the star formation cycle.…