Related papers: The chemistry of interstellar molecules containing…
A mechanism based on the penetration of interstellar ultraviolet photons into the inner layers of clumpy circumstellar envelopes around AGB stars is proposed to explain the non-equilibrium chemistry observed in such objects. We show through…
In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…
Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…
Molecular hydrogen (H$_2$) is by far the most abundant molecule in the Universe. However, due to the low emissivity of H$_2$, carbon monoxide (CO) is widely used instead to trace molecular gas in galaxies. The relative abundances of these…
We introduce a stochastic halo formation model to compute the early chemical enrichment of the interstellar medium (ISM) of the halo. Contrary to 1-zone chemical evolution models, we are able to resolve local inhomogeneities in the ISM…
We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…
H2 is the simplest and the most abundant molecule in the ISM, and its formation precedes the formation of other molecules. Understanding the dynamical influence of the environment and the interplay between the thermal processes related to…
Molecular clouds are essentially made up of atomic and molecular hydrogen, which in spite of being the simplest molecule in the ISM plays a key role in the chemical evolution of molecular clouds. Since its formation time is very long, the…
Localised regions of enhanced emission from HCO+, NH3 and other species near Herbig-Haro objects (HHOs) have been interpreted as arising in a photochemistry stimulated by the HHO radiation on high density quiescent clumps in molecular…
The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally…
We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…
This study uses cool dwarfs as sources with which to probe fluorine abundances via HF. This molecule is detected for the first time in young K-M dwarf members of an OB association. Fluorine, oxygen, and carbon abundances were derived from…
This paper presents the first substantial study of the chemistry of the envelopes around a sample of 18 low-mass pre- and protostellar objects for which physical properties have previously been derived from radiative transfer modeling of…
We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen within diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photo-…
The cosmic abundance of hydrides depends critically on high-energy UV, X-ray, and particle irradiation. Here we study hydrides in star-forming regions where irradiation by the young stellar object can be substantial, and density and…
The elemental depletion of interstellar sulfur from the gas phase has been a recurring challenge for astrochemical models. Observations show that sulfur remains relatively non-depleted with respect to its cosmic value throughout the diffuse…
We use a simple one-zone model of the thermal and chemical evolution of interstellar gas to study whether molecular hydrogen (H2) is ever an important coolant of the warm, diffuse interstellar medium (ISM). We demonstrate that at solar…
The astrochemistry of the HnO+ (n=1..3) ions is important as the main gas-phase formation route for water, and as tracer of the interstellar ionization rate by cosmic rays and other processes. While interstellar H3O+ has been known since…
We present a study of the elemental depletion in the interstellar medium. We combined the results of a Galatic model describing the gas physical conditions during the formation of dense cores with a full-gas-grain chemical model. During the…
We have compiled a sample of 699 stars from the recent literature with detailed chemical abundance information (spanning -4.2 < [Fe/H] < +0.3), and we compute their space velocities and Galactic orbital parameters. We identify members of…