Related papers: The chemistry of interstellar molecules containing…
ABRIDGED: Context: HI and CO large scale surveys of the Milky Way trace the diffuse atomic clouds and the dense shielded regions of molecular hydrogen clouds. However, until recently, we have not had spectrally resolved C+ surveys to…
An accurate treatment of the multiphase interstellar medium (ISM) in hydrodynamic galaxy simulations requires that we follow not only the thermal evolution of the gas, but also the evolution of its chemical state, including its molecular…
Absorption lines from the molecules OH+, H2O+, and H3+ have been observed in a diffuse molecular cloud along a line of sight near W51 IRS2. We present the first chemical analysis that combines the information provided by all three of these…
We present column density measurements of the HD molecule in the interstellar gas toward 17 Galactic stars. The values for the seven most heavily reddened sightlines, with E(B-V) = 0.38-0.72, are derived from observations with the Far…
Interstellar hydrides -- that is, molecules containing a single heavy element atom with one or more hydrogen atoms -- were among the first molecules detected outside the solar system. They lie at the root of interstellar chemistry, being…
It is a fact that interstellar formation processes are thermodynamically affected. Based on this, the seven heterocycles; imidazole, pyridine, pyrimidine, pyrrole, quinoline, isoquinoline and furan that have been searched for from different…
We present the analysis of a sub-DLA system (log N(H^0)=20.0+/-0.15, z_abs=2.69) toward SDSS J123714+064759 (z_em=2.78). Using the VLT/UVES and X-shooter spectrographs, we detect H2, HD and CO molecules in absorption with log…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…
Most stars in the Galaxy, including the Sun, were born in high-mass star-forming regions. It is hence important to study the chemical processes in these regions to better understand the chemical heritage of both the Solar System and most…
We have observed the HC3N (J=10-9) and N2H+ (J=1-0) lines toward the Vela C molecular clouds with the Mopra 22 m telescope to study chemical characteristics of dense cores. The intensity distributions of these molecules are similar to each…
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code…
We investigate interstellar absorption from molecular hydrogen (H_2) and metals in an intermediate-velocity cloud (IVC) in the direction of the LMC star Sk -68 80 (HD 36521), based on data from the Far Ultraviolet Spectroscopic Explorer…
Nine HII regions of the LMC were mapped in 13CO(1--0) and three in 12CO(1--0) to study the physical properties of the interstellar medium in the Magellanic Clouds. For N113 the molecular core is found to have a peak position which differs…
Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…
We measured $^{35}$Cl abundances in 52 M giants with metallicities between -0.5 $<$ [Fe/H] $<$ 0.12. Abundances and atmospheric parameters were derived using infrared spectra from CSHELL on the IRTF and from optical echelle spectra. We…
Chlorine abundances are reported in 15 evolved giants and one M dwarf in the solar neighborhood. The Cl abundance was measured using the vibration-rotation 1-0 P8 line of H$^{35}$Cl at 3.69851 $\mu$m. The high resolution L-band spectra were…
We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer (LWS) of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2 - 1 line of HF in absorption toward the…
As building blocks of dust, rocky planets, and even complex life, the chemical elements heavier than hydrogen (H) and helium (He) - called "metals" in astronomy - play an essential role in our Universe and its evolution. Up to Fe and Ni,…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
Recent submillimeter and far-infrared wavelength observations of absorption in the rotational ground-state lines of various simple molecules against distant Galactic continuum sources have opened the possibility of studying the chemistry of…