Related papers: Generalization of the Second Law for a Nonequilibr…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
A heat engine undergoes a cyclic operation while in equilibrium with the net result of conversion of heat into work. Quantum effects such as superposition of states can improve an engine's efficiency by breaking detailed balance, but this…
It is shown that the laws of thermodynamics are extremely robust under generalizations of the form of entropy. Using the Bregman-type relative entropy, the Clausius inequality is proved to be always valid. This implies that thermodynamics…
The local entropy of a nonequilibrium system of independent fermions is investigated, and analyzed in the context of the laws of thermodynamics. It is shown that the local temperature and chemical potential can only be expressed in terms of…
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…
We proved when random-variable fluctuations obey the central limit theorem the equality of the uncertainty relation corresponds to the thermodynamic equilibrium state. The inequality corresponds to the thermodynamic non-equilibrium state.…
By considering an explicit nonequilibrium model, we analyze the statistics of the irreversible work, $w_{\rm irr}$, and irreversible entropy production, $\Delta_i s$, within the stochastic energetics framework. Restating the second law of…
It has long been known that, fundamentally different from a large body of rarefied gas, when a Knudsen gas is immersed in a thermal bath, it may never reach thermal equilibrium. The root cause is nonchaoticity: as the particle-particle…
We show that there exists a natural way to define a condition of generalized thermal equilibrium between systems governed by Tsallis thermostatistics, under the hypotheses that i) the coupling between the systems is weak, ii) the structure…
A proof of the relativistic $H$-theorem by including nonextensive effects is given. As it happens in the nonrelativistic limit, the molecular chaos hypothesis advanced by Boltzmann does not remain valid, and the second law of thermodynamics…
This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…
In earlier work we presented a foundation for the Second Law of Classical Thermodynamics in terms of the Entropy Principle. More precisely, we provided an empirically accessible axiomatic derivation of an entropy function defined on all…
The first part of this paper is a condensed synthesis of the matter presented in several previous ones. It begins with an argumentation showing that the first and second laws of thermodynamics are incompatible with one another if they are…
We investigate the validity of the generalized second law of thermodynamics, in the cosmological scenario where dark energy interacts with both dark matter and radiation. Calculating separately the entropy variation for each fluid component…
It was first suggested by David Z. Albert that the existence of a real, physical non-unitary process (i.e., "collapse") at the quantum level would yield a complete explanation for the Second Law of Thermodynamics (i.e., the increase in…
Even though the second law of thermodynamics holds the supreme position among the laws of nature, as stated by many distinguished scientists, notably Eddington and Einstein, its position appears to be also quite peculiar. Given the atomic…
Starting from the basic prescriptions of the Tsallis' nonextensive thermostatistics, i.e. generalized entropy and normalized q-expectation values, we study the relativistic nonextensive thermodynamics and derive a Boltzmann transport…
We consider a previously proposed non-extensive statistical mechanics in which the entropy depends only on the probability, this was obtained from a f(\beta) distribution and its corresponding Boltzmann factor. We show that the first term…