Related papers: Generalization of the Second Law for a Nonequilibr…
In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…
For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…
We extend Jarzynski's work relation and the second law of thermodynamics to a heat conducting system which is operated by an external agent. These extensions contain a new non equilibrium contribution expressed as the violation of the…
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
In Nonequilibrium Thermodynamics and Information Theory, the relative entropy (or, KL divergence) plays a very important role. Consider a H\"older Jacobian $J$ and the Ruelle (transfer) operator $\mathcal{L}_{\log J}.$ Two equilibrium…
People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…
In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…
It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…
$H$-theorem states that the entropy production is nonnegative and, therefore, the entropy of a closed system should monotonically change in time. In information processing, the entropy production is positive for random transformation of…
Equilibrium thermodynamics is combined with Jarzynski's irreversible work theorem to quantify the excess entropy produced by irreversible processes. The resulting rectified form of the second law parallels the first law, in the sense that…
We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…
The Kelvin-Planck statement of the Second Law of Thermodynamics is a stricture on the nature of heat receipt by any body suffering a cyclic process. It makes no mention of temperature or of entropy. Beginning with a Kelvin-Planck statement…
We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…
We consider the Non-Equilibrium Steady State induced by two infinite quantum thermal reservoirs at different temperatures and derive an inequality giving the upper bound of the work extracted by cyclic operations. This upper bound tends to…
The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…
We design a heat engine with multi-heat-reservoir, ancillary system and quantum memory. We then derive an inequality related with the second law of thermodynamics, and give a new limitation about the work gain from the engine by analyzing…
Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…
We derive a generalization of the Second Law of Thermodynamics that uses Bayesian updates to explicitly incorporate the effects of a measurement of a system at some point in its evolution. By allowing an experimenter's knowledge to be…