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The entropy of a thermally isolated system should not decrease after a quench or external driving. For a classical system following Hamiltonian dynamics, we show how this statement emerges for a large system in the sense that the extensive…

Statistical Mechanics · Physics 2020-12-24 Udo Seifert

Bridging the second law of thermodynamics and microscopic reversible dynamics has been a longstanding problem in statistical physics. We here address this problem on the basis of quantum many-body physics, and discuss how the entropy…

Statistical Mechanics · Physics 2018-01-03 Kazuya Kaneko , Eiki Iyoda , Takahiro Sagawa

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

Mathematical Physics · Physics 2015-06-19 Elliott H. Lieb , Jakob Yngvason

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

We extend classical coarse-grained entropy, commonly used in many branches of physics, to the quantum realm. We find two coarse-grainings, one using measurements of local particle numbers and then total energy, and the second using local…

Quantum Physics · Physics 2019-01-17 Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

Quantum Physics · Physics 2015-03-30 David M. Rogers

Several results of black holes thermodynamics can be considered as firmly founded and formulated in a very general manner. From this starting point we analyse in which way these results may give us the opportunity to gain a better…

General Relativity and Quantum Cosmology · Physics 2009-11-11 J. P. Badiali

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

Entropy in thermodynamics is an extensive quantity, whereas standard methods in statistical mechanics give rise to a non-extensive expression for the entropy. This discrepancy is often seen as a sign that basic formulas of statistical…

History and Philosophy of Physics · Physics 2012-09-06 Dennis Dieks

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

On the basis of the balance equations for energy-momentum, spin, particle and entropy density, an approach is considered which represents a comparatively general framework for special- and general-relativistic continuum thermodynamics. In…

General Relativity and Quantum Cosmology · Physics 2009-11-13 W. Muschik , H. -H. v. Borzeszkowski

We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by…

Statistical Mechanics · Physics 2008-04-15 V. Garcia-Morales , J. Pellicer , J. A. Manzanares

Expected utility maximization problems in mathematical finance lead to a generalization of the classical definition of entropy. It is demonstrated that a necessary and sufficient condition for the second law of thermodynamics to operate is…

Probability · Mathematics 2007-05-23 Wojciech Slomczynski , Tomasz Zastawniak

The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…

High Energy Physics - Theory · Physics 2017-02-20 Paolo Glorioso , Hong Liu

We consider critical models in one dimension. We study the ground state in thermodynamic limit [infinite lattice]. Following Bennett, Bernstein, Popescu, and Schumacher, we use the entropy of a sub-system as a measure of entanglement. We…

Strongly Correlated Electrons · Physics 2009-11-10 Vladimir Korepin

The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…

Quantum Physics · Physics 2025-11-24 Xue-Yi Guo

We investigate numerically the low temperature equilibration of glassy systems via non-local Monte Carlo methods. We re-examine several systems that have been studied previously and investigate new systems in order to test the performance…

Soft Condensed Matter · Physics 2007-05-23 Yisroel Brumer , David R. Reichman

We numerically determine the entropy for heat-conducting states, which is connected to the so-called excess heat considered as a basic quantity for steady-state thermodynamics in nonequilibrium. We adopt an efficient method to estimate the…

Statistical Mechanics · Physics 2016-08-17 Yoshiyuki Chiba , Naoko Nakagawa