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New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

Statistical Mechanics · Physics 2021-05-05 Paul M. Riechers , Mile Gu

The thermodynamic limit of the internal energy and the entropy of the system of quantum interacting particles in random medium is shown to exist under the crucial requirements of stability and temperedness of interactions. The energy turns…

Mathematical Physics · Physics 2012-01-24 Nikolaj A. Veniaminov

Many theoretical expressions of dissipation along non-equilibrium processes have been proposed. However, they have not been fully verified by experiments. Especially for systems strongly interacting with environments the connection between…

Statistical Mechanics · Physics 2019-12-03 Ketan Goyal , Xian He , Ryoichi Kawai

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…

Statistical Mechanics · Physics 2015-06-17 Shin-ichi Sasa

The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…

Statistical Mechanics · Physics 2023-05-18 Arnaldo Spalvieri

The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…

Statistical Mechanics · Physics 2020-08-21 Gil Ariel , Haim Diamant

We use the general statement of the second law applied to an isolated system, the glass in an extremely large medium, to prove that the entropy of the glass must decrease with time during its relaxation towards the supercooled liquid state.…

Disordered Systems and Neural Networks · Physics 2009-09-04 P. D. Gujrati

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

We study the entropy of small subsystems in thermalizing quantum many-body systems governed by local Hamiltonians. Assuming the eigenstate thermalization hypothesis, we derive an analytical formula for the von Neumann entropy of…

Statistical Mechanics · Physics 2025-02-03 Yichen Huang

Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…

Quantum Physics · Physics 2023-11-06 Uwe Hohm , Christoph Schiller

The local entropy of a nonequilibrium system of independent fermions is investigated, and analyzed in the context of the laws of thermodynamics. It is shown that the local temperature and chemical potential can only be expressed in terms of…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Charles A. Stafford , Abhay Shastry

The 2nd law of thermodynamics yields an irreversible increase in entropy until thermal equilibrium is achieved. This irreversible increase is often assumed to require large and complex systems to emerge from the reversible microscopic laws…

Statistical Mechanics · Physics 2023-11-21 Ralph V. Chamberlin

Entropy is a very useful concept from physics that tries to explain how a system behaves from a point of view of the thermodynamics. However, there are two ways to explain entropy, and it depends on if we are studying a microsystem or a…

General Finance · Quantitative Finance 2024-07-02 Martin Pomares Calero

In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting…

Quantum Physics · Physics 2020-06-01 Dana Faiez , Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma