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Polarized Raman scattering measurements have been performed on Na0.5CoO2 single crystal from 8 to 305 K. Both the A1g and E1g phonon modes show a softening below Tc1 ~ 83 K. Additionally, the A1g phonon mode, which is forbidden in the…

Strongly Correlated Electrons · Physics 2008-02-07 Q. M. Zhang , M. an , S. K. Yuan , Y. Wu , D. Wu , J. L. Luo , N. L. Wang , W. Bao , Y. N. Wang

Nanotubed titanic acid (H2Ti2O4(OH)2) was prepared from nanotubed sodium titanate (Na2Ti2O4(OH)2) by an ion exchange reaction in a pH=1 HCl solution. The effect of annealing temperature on the morphology, structure and photocatalytic…

Materials Science · Physics 2010-09-16 Min Zhang , Zhensheng Jin , Jingwei Zhang , Xinyong Guo , Jianjun Yang , Wei Li , Xiaodong Wang , Zhijun Zhang

Sub-wavelength laser induced periodic surface structures (LIPSS-Sticks) created by ultrashort pulsed laser irradiation on the surface of titanium are used for the first time to template the electrochemical growth of titanium dioxide…

Applied Physics · Physics 2020-08-04 Rakesh Arul , Junzhe Dong , M. Cather Simpson , Wei Gao

We report magnetic, optical and oxidation states of oxygen deficient TiO$_{2-\delta}$ nanoparticles (NPs) synthesized by environment-friendly green route using Phyllanthus niruri (PN) whole plant extract instead of leaf extract. Rietveld…

Highly ordered and self supported anatase TiO2 nanoparticle chains were fabricated by calcining conformally TiO2 coated multi-walled carbon nanotubes (MWCNTs). During annealing, the thin tubular TiO2 coating that was deposited onto the…

In this work we study the optical properties, by means of the transfer matrix method, of one-dimensional photonic crystals in which layers of silica nanoparticles are alternated with layers of indium tin oxide nanoparticle (ITO) / titania…

Optics · Physics 2019-02-15 Ilka Kriegel , Francesco Scotognella

Anatase TiO2 (a-TiO2) exhibits a strong X-ray absorption linear dichroism with the X-ray incidence angle in the pre-edge, the XANES and the EXAFS at the titanium K-edge. In the pre-edge region the behaviour of the A1-A3 and B peaks,…

The wealth of properties of titanium dioxide relies on its various polymorphs and on their mixtures coupled with a sensitivity to crystallographic orientations. It is therefore pivotal to set out methods that allow surface structural…

We report a direct observation of the microscopic origin of the bipolar resistive switching behavior in nanoscale titanium oxide films. Through a high-resolution transmission electron microscopy, an analytical TEM technique using…

Materials Science · Physics 2015-05-13 Hu Young Jeong , Jeong Yong Lee , Sung-Yool Choi , Jeong Won Kim

Anatase TiO2 is an indirect band-gap material with large degree of sub-stoichiometry, selective excitation of its native defect reveals polychromatic emission in blue, green and red spectral regions due to self trapped excitons and…

Materials Science · Physics 2021-10-22 Neha Luhakhra , Sanjiv Kumar Tiwari

We report the existence of broad and weakly asymmetric features in the high-energy (G) Raman modes of freely suspended metallic carbon nanotubes of defined chiral index. A significant variation in peak width (from 12 cm-1 to 110 cm-1) is…

An interesting interplay between two different modifiers and the surface of titanium dioxide leads to a significant change in photoelectrochemical properties of the designed hybrid materials. The semiconductor is photosensitized by one of…

Materials Science · Physics 2018-10-25 K. Pilarczyk , K. Lewandowska , K. Mech , M. Kawa , M. Gajewska , B. Barszcz , A. Bogucki , A. Podborska , K. Szaciłowski

Thin films of Co-TiO2 are deposited on silicon and quartz substrates using Pulse Laser Deposition (PLD) process at various oxygen partial pressures ranging from 6.6 x 10-3 Pascals (Pa) to 53 Pa. Crystal structure, transport and magnetic…

Materials Science · Physics 2007-05-23 Bakhtyar Ali , Abdul K Rumaiz , S. Ismat Shah , Arif Ozbay , Edmund R Nowak

Small polaron formation in transition metal oxides, like the prototypical material rutile TiO$_2$, remains a puzzle and a challenge to simple theoretical treatment. In our combined experimental and theoretical study, we examine this problem…

Materials Science · Physics 2017-12-06 Grigory Kolesov , Boris A. Kolesov , Efthimios Kaxiras

Nanocrystals of indium oxide (In$_2$O$_3$) with sizes below 10 nm were prepared in alumina matrixes by using a co-pulverization method. The used substrates such as borosilicate glasses or (100) silicon as well as the substrate temperatures…

The Raman shifts of nanocrystalline GaSb excited by an Ar+ ion laser of wavelengths 514.5, 496.5, 488.0, 476.5, and 457.9 nm are studied by experiment and explained by phonon confinement, tensile stress, resonance Raman scattering and…

A crack free and high structural quality Sr2Nb2O7 single crystals were grown by the optical float zone method using optimized growth parameters. Laue pattern confirms single crystalline nature of the grown crystal. Temperature dependent…

The ability to control porosity in oxide thin films is one of the key factors that determine their properties. Despite the abundance of dry processes for the synthesis of oxide porous layers, the high porosity range is typically achieved by…

Thin coatings of Chromium oxide have been used for applications as absorbing material in solar cells, as protections for magnetic data recording devices and as shields in flexible solar cells. Thin coatings of pure chromium were vacuum…

Low dimensional materials are critical for enabling next generation applications that are central to addressing critical global challenges. Titanium dioxide nanostructures stand out due to their structural versatility and relevance to…