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Positively charged cluster ions of phosphorus were formed upon electron ionization of doped helium nanodroplets. The vapors of red phosphorus and a phosphate sample were picked up into neutral and charged helium nanodroplets. Independent on…

An experimental approach is presented that allows for the incorporation of large mass/charge selected ions in liquid helium droplets. It is demonstrated that droplets can be efficiently doped with a mass/charge selected amino acid as well…

Atomic and Molecular Clusters · Physics 2010-09-30 Frauke Bierau , Peter Kupser , Gerard Meijer , Gert von Helden

Photoionization spectroscopy and mass spectrometry of doped helium (He) nanodroplets rely on the ability to efficiently detect ions and/or electrons. Using a commercial quadrupole mass spectrometer and a photoelectron-photoion coincidence…

Evaporative cooling of helium nanodroplets is studied with a statistical rate model that includes, for the first time, angular momentum conservation as a constraint on the accessible droplet states. It is found that while the final…

Chemical Physics · Physics 2009-11-10 Kevin K. Lehmann , Adriaan M. Dokter

We present systematic results, based on density functional calculations, for the structure and energetics of $^3$He and $^4$He nanodroplets doped with alkaline earth atoms. We predict that alkaline earth atoms from Mg to Ba go to the center…

Soft Condensed Matter · Physics 2016-09-28 A. Hernando , R. Mayol , M. Pi , M. Barranco , F. Ancilotto , O. Bünermann , F. Stienkemeier

The relaxation dynamics of superexcited superfluid He nanodroplets is thoroughly investigated by means of extreme-ultraviolet (XUV) femtosecond electron and ion spectroscopy complemented by time-dependent density functional theory (TDDFT).…

We thoroughly investigate vibrational quantum dynamics of dimers attached to He droplets motivated by recent measurements with K-2 [1]. For those femtosecond pump-probe experiments, crucial observed features are not reproduced by gas phase…

Chemical Physics · Physics 2012-03-15 Martin Schlesinger , Walter. T. Strunz

The spectroscopy of free radicals and radical containing entrance-channel complexes embedded in superfluid helium nano-droplets is reviewed. The collection of dopants inside individual droplets in the beam represents a micro-canonical…

Atomic and Molecular Clusters · Physics 2007-08-02 Jochen Küpper , Jeremy M. Merritt

The time-dependent kinetics of formation and evolution of nano-size atomic clusters is investigated and illustrated with the nucleation dynamics of ion-seed Ar$_n$H$^+$ particles. The rates of growth and degradation of Ar-atomic shells…

Atomic and Molecular Clusters · Physics 2022-02-23 M. G. Rozman , M. Bredice , J. Smucker , H. R. Sadeghpour , D. Vrinceanu , R. Cote , V. Kharchenko

Alkali metal dimers attached to the surface of helium nanodroplets are found to be efficiently doubly ionized by electron transfer-mediated decay (ETMD) when photoionizing the helium droplets. This process is evidenced by detecting in…

Ion-molecule reactions between clusters of H$_2$/D$_2$ and O$_2$ in liquid helium nanodroplets were initiated by electron-induced ionization (at 70 eV). Reaction products were detected by mass spectrometry and can be explained by a primary…

Atomic and Molecular Clusters · Physics 2018-05-09 Michael Renzler , Stefan Ralser , Lorenz Kranabetter , Erik Barwa , Paul Scheier , Andrew M. Ellis

A significant fraction of superfluid helium nanodroplets produced in a free-jet expansion have been observed to gain high angular momentum resulting in large centrifugal deformation. We measured single-shot diffraction patterns of…

Optimal control techniques combined with femtosecond laser pulse shaping are applied to steer and enhance the strong-field induced emission of highly charged atomic ions from silver clusters embedded in helium nanodroplets. With light…

Using variable temperature scanning tunneling microscopy and dI/dz barrier height spectroscopy, the structure of water on h-BN/Rh(111) nanomesh has been investigated. Below its desorption temperature, two distinct phases of water…

Neutral alkali clusters efficiently capture low-energy electrons with the aid of long-range polarization attraction. Upon attachment, the electron affinity and kinetic energy are dissipated into vibrations, heating the cluster and…

Atomic and Molecular Clusters · Physics 2011-12-14 Roman Rabinovitch , Klavs Hansen , Vitaly V. Kresin

Theoretical studies on the geometry, electronic structure and spin multiplicity of Sc, Ti and V doped Na$_n$ (n = 4, 5, 6) clusters have been carried out within a gradient corrected density functional approach. Two complementary approaches…

Materials Science · Physics 2009-11-13 Kalpataru Pradhan , Prasenjit Sen , J. U. Reveles , S. N. Khanna

The classical integral cross sections of large superfluid 4He_N droplets and the number of atoms in the droplets (N=10^3-10^4) have been measured in molecular beam scattering experiments. These measurements are found to be in good agreement…

Condensed Matter · Physics 2009-10-30 Jan Harms , J. Peter Toennies , Franco Dalfovo

Using first-principles calculations, we perform a search for high-capacity hydrogen storage media based on individually dispersed calcium atoms on doped or defective carbon nanotubes. We find that up to six H2 molecules can bind to a Ca…

Materials Science · Physics 2009-01-20 Hoonkyung Lee , Jisoon Ihm , Marvin L. Cohen , Steven G. Louie

Optical tweezers, the three-dimensional confinement of a nanoparticle by a strongly focused beam of light, have been widely employed in investigating biomaterial nanomechanics, nanoscopic fluid properties, and ultrasensitive detections in…

The dynamics of vibrational wave packets excited in K$_2$ dimers attached to superfluid helium nanodroplets is investigated by means of femtosecond pump-probe spectroscopy. The employed resonant three-photon-ionization scheme is studied in…

Atomic and Molecular Clusters · Physics 2009-11-11 P. Claas , G. Droppelmann , C. P. Schulz , M. Mudrich , F. Stienkemeier