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The effects of interactions between He- and clusters of fullerenes in helium nanodroplets are described. Electron transfer from $He^{-}$ to $(C_{60})_n$ and $(C_{70})_n$ clusters results in the formation of the corresponding fullerene…

Atomic and Molecular Clusters · Physics 2016-05-03 A. Mauracher , M. Daxner , S. E. Huber , J. Postler , M. Renzler , S. Denifl , P. Scheier , A. M. Ellis

Alkali atoms do not stably embed in liquid helium-4 because the interatomic attractive potential is unable to overcome the short-range Pauli repulsion of the s electrons and the surface tension cost of the surrounding bubble. Similarly,…

Atomic and Molecular Clusters · Physics 2010-02-01 Casey Stark , Vitaly V. Kresin

There has been notable uncertainty regarding the degree of solvation of alkaline-earth atoms, especially Mg, in free He-4 nanodroplets. We have measured the electron energy dependence of the ionization yield of picked-up atoms. There is a…

Other Condensed Matter · Physics 2011-11-10 Yanfei Ren , Vitaly V. Kresin

High-resolution mass spectra of helium droplets doped with gold and ionized by electrons reveal He$_n$Au$^+$ cluster ions. Additional doping with heavy noble gases results in NenAu+, Ar$_n$Au$^+$, Kr$_n$Au$^+$, and Xe$_n$Au$^+$ cluster…

Atomic and Molecular Clusters · Physics 2022-11-11 Paul Martini , Lorenz Kranabetter , Marcelo Goulart , Bilal Rasul , Michael Gatchell , Paul Scheier , Olof Echt

Helium nanodroplets are ideal model systems to unravel the complex interaction of condensed matter with ionizing radiation. Here we study the effect of purely elastic electron scattering on angular and energy distributions of photoelectrons…

The utility of a continuous beam of He droplets for the assembly and surface deposition of Ag clusters, <N(Ag)> ~ 300 - 6 000, is studied with transmission electron microscopy. Images of the clusters on amorphous carbon substrates obtained…

Atomic and Molecular Clusters · Physics 2016-09-28 Evgeny Loginov , Luis F. Gomez , Andrey F. Vilesov

The energy and angular momentum of both straight and curved vortex states of a helium nanodroplet are examined as a function of droplet size. For droplets in the size range of many experiments, it is found that during the pickup of heavy…

Condensed Matter · Physics 2007-05-23 Kevin K. Lehmann , Roman Schmied

Recent pump-probe experiments [Albrechtsen {\em et al.}, Nature {\bf 623}, 319 (2023)] have explored the gradual solvation of sodium cations in contact with helium nanodroplets, using a fully solvated xenon atom as a probe exerting a…

Chemical Physics · Physics 2024-09-26 F. Calvo

Much of our knowledge about dynamics and functionality of molecular systems has been achieved with femtosecond time-resolved spectroscopy. Despite extensive technical developments over the past decades, some classes of systems have eluded…

Chemical Physics · Physics 2020-03-25 Bernhard Thaler , Miriam Meyer , Pascal Heim , Markus Koch

While sub-mm melt droplets should rapidly lose alkali elements in a vacuum at liquidus temperatures, chondrules are only modestly depleted in them (by less than one order of magnitude). The detection of sodium in olivine cores has…

Earth and Planetary Astrophysics · Physics 2026-01-22 Emmanuel Jacquet , Yves Marrocchi , Sébastien Charnoz

Clusters and nanodroplets hold the promise of enhancing high-order nonlinear optical effects due to their high local density. However, only moderate enhancement has been demonstrated to date. Here, we report the observation of energetic…

Neon cluster ions Ne$_s^+$ grown in pre-ionized, mass-to-charge selected helium nanodroplets (HNDs) reveal a strong enrichment of the heavy isotope $^{22}$Ne that depends on cluster size s and the experimental conditions. For small sizes…

Atomic and Molecular Clusters · Physics 2022-11-18 Lukas Tiefenthaler , Siegfried Kollotzek , Michael Gatchell , Klavs Hansen , Paul Scheier , Olof Echt

We present an experimental study of the dynamics following the photo-excitation and subsequent photo-ionization of single Cs atoms on the surface of helium nanodroplets. The dynamics of excited-Cs-atom desorption and re-adsorption as well…

Atomic and Molecular Clusters · Physics 2021-10-18 Nicolas Rendler , Audrey Scognamiglio , Katrin Dulitz , Frank Stienkemeier , Manuel Barranco , Marti Pí , Nadine Halberstadt

This review has two principal aims. The first of these is to provide a comprehensive overview of the applications of HNDs in the study of collections of atoms and molecules, i.e. clusters and complexes. These clusters and complexes must…

Atomic and Molecular Clusters · Physics 2018-05-10 A. Mauracher , O. Echt , A. M. Ellis , S. Yang , D. K. Bohme , J. Postler , A. Kaiser , S. Denifl , P. Scheier

We demonstrate a novel method to ionize molecules or molecular clusters by proton transfer at temperatures below 1 K. The method yields nascent ions and largely eliminates secondary reactions, even for notoriously "delicate" molecules.…

Chemical Physics · Physics 2022-11-16 Lukas Tiefenthaler , Siegfried Kollotzek , Andrew M. Ellis , Paul Scheier , Olof Echt

We have experimentally studied the electronic $3p-> 3s$ excitation of Na atoms attached to $^3$He droplets by means of laser-induced fluorescence as well as beam depletion spectroscopy. From the similarities of the spectra (width/shift of…

Soft Condensed Matter · Physics 2009-11-10 R. Mayol , F. Ancilotto , M. Barranco , O. Bünermann , M. Pi , F. Stienkemeier

We study the dynamics of avalanche ionization of pure helium nanodroplets activated by a weak extreme-ultraviolet (XUV) pulse and driven by an intense near-infrared (NIR) pulse. In addition to a transient enhancement of ignition of a…

Using a density functional method, we investigate the properties of liquid 4He droplets doped with atoms (Ne and Xe) and molecules (SF_6 and HCN). We consider the case of droplets having a quantized vortex pinned to the dopant. A liquid…

Condensed Matter · Physics 2009-10-31 Franco Dalfovo , Ricardo Mayol , Marti Pi , Manuel Barranco

Anions are formed by electron attachment to helium nanodroplets doped with N$_2$. The most prominent ion series is due to odd-numbered N$_m$$^{-}$ with 3 $\le$ m < 140. Neither N$^{-}$ nor N$_2$$^{-}$ are observed. An appearance energy of…

Atomic and Molecular Clusters · Physics 2018-05-03 Nikolaus Weinberger , Johannes Postler , Paul Scheier , Olof Echt

Neutron diffraction and magnetic susceptibility studies of orthorhombic single crystal {\Ksub} confirm the three dimensional (3D) C-type antiferromagnetic (AFM) ordering of the Mn$^{2+}$ moments at $T_{\rm N}=305 \pm 3$ K which is slightly…

Strongly Correlated Electrons · Physics 2019-07-30 Yong Liu , Farhan Islam , Kevin W. Dennis , Wei Tian , Benjamin G. Ueland , Robert J. McQueeney , David Vaknin