English
Related papers

Related papers: Alkali-helium snowball complexes formed on helium …

200 papers

We use a novel technique to solvate silver cations in small clusters of noble gases. The technique involves formation of large, superfluid helium nanodroplets that are subsequently electron ionized, mass-selected by deflection in an…

Atomic and Molecular Clusters · Physics 2022-11-11 Masoomeh Mahmoodi-Darian , Paul Martini , Lukas Tiefenthaler , Jaroslav Kočišek , Paul Scheier , Olof Echt

Sequential ionization of fullerene cluster ions (C$_{60}$)$_{n}^{+}$ within multiply-charged helium nanodroplets leads to the intriguing phenomenon of forming and stabilizing doubly- and triply-charged fullerene oligomers. Surprisingly, we…

Atomic and Molecular Clusters · Physics 2023-12-11 Lisa Ganner , Stefan Bergmeister , Lucas Lorenz , Milan Ončák , Paul Scheier , Elisabeth Gruber

By means of the exact Path Integral Monte Carlo method we have performed a detailed microscopic study of $^4$He nanodroplets doped with an argon ion, Ar$^+$, at $T=0.5$ K. We have computed density profiles, energies, dissociation energies…

Atomic and Molecular Clusters · Physics 2015-06-23 Filippo Tramonto , Paolo Salvestrini , Marco Nava , Davide E. Galli

Helium nanodroplets are widely used as a cold, weakly interacting matrix for spectroscopy of embedded species. In this work we excite or ionize doped He droplets using synchrotron radiation and study the effect onto the dopant atoms…

Helium nanodroplets doped with polar molecules are studied by electrostatic deflection. This broadly applicable method allows even polyatomic molecules to attain sub-Kelvin temperatures and nearly full orientation in the field. The…

Atomic and Molecular Clusters · Physics 2019-07-26 John W. Niman , Benjamin S. Kamerin , Daniel J. Merthe , Lorenz Kranabetter , Vitaly V. Kresin

The ionization dynamics of helium droplets in a wide size range from 220 to 10^6 He atoms irradiated with intense femtosecond extreme ultraviolet (XUV) pulses of 10^9 {\div} 10^{12} W/cm2 power density is investigated in detail by…

Alkali dimers, $\mathrm{Ak}_2$, located on the surface of a helium nanodroplet, are set into rotation through the polarizability interaction with a nonresonant 1-ps-long laser pulse. The time-dependent degree of alignment is recorded using…

Helium nanodroplets ("HNDs") are widely used for forming tailor-made clusters and molecular complexes in a cold, transparent, and weakly-interacting matrix. Characterization of embedded species by mass spectrometry is often complicated by…

Atomic and Molecular Clusters · Physics 2024-01-15 S. De , A. R. Abid , J. D. Asmussen , L. Ben Ltaief , K. Sishodia , A. Ulmer , H. B. Pedersen , S. R. Krishnan , M. Mudrich

Metal-fullerene compounds are characterized by significant electron transfer to the fullerene cage, giving rise to an electric dipole moment. We use the method of electrostatic beam deflection to verify whether such reactions take place…

Atomic and Molecular Clusters · Physics 2022-04-26 John W. Niman , Benjamin S. Kamerin , Thomas H. Villers , Thomas M. Linker , Aiichiro Nakano , Vitaly V. Kresin

A new setup for doping helium nanodroplets by means of laser ablation at kilohertz repetition rate is presented. The doping process is characterized and two distinct regimes of laser ablation are identified. The setup is shown to be…

Atomic and Molecular Clusters · Physics 2011-12-19 M. Mudrich , B. Forkl , S. Mueller , M. Dvorak , O. Buenermann , F. Stienkemeier

When fragile molecules such as glycine, polyglicine, alkanes, and alkanethiols are embedded in liquid helium nanodroplets, electron-impact ionization of the beam leads to fragmentation which is as extensive as that of isolated gas-phase…

Atomic and Molecular Clusters · Physics 2008-02-23 Yanfei Ren , Vitaly V. Kresin

The mechanism of ionization of helium droplets has been investigated in numerous reports but one observation has not found a satisfactory explanation: How are $He^+$ ions formed and ejected from undoped droplets at electron energies below…

Atomic and Molecular Clusters · Physics 2016-11-30 Michael Renzler , Matthias Daxner , Nikolaus Weinberger , Stephan Denifl , Paul Scheier , Olof Echt

We have investigated how helium atoms are distributed within a mixed $^3$He$_{N_3}$-$^4$He$_{N_4}$ large drop with $N_3 \gg N_4$. For drops doped with a SF$_6$ molecule or a Xe atom, we have found that the number of $^3$He atoms within the…

Condensed Matter · Physics 2009-10-31 Marti Pi , Ricardo Mayol , Manuel Barranco

Mixed $^3$He-$^4$He droplets created by hydrodynamic instability of a cryogenic fluid-jet may acquire angular momentum during their passage through the nozzle of the experimental apparatus. These free-standing droplets cool down to very low…

Quantum Gases · Physics 2020-08-12 Marti Pi , Francesco Ancilotto , Jose' Maria Escartin , Ricardo Mayol , Manuel Barranco

Long-range intermolecular forces are able to steer polar molecules submerged in superfluid helium nanodroplets into highly polar metastable configurations. We demonstrate that the presence of such special structures can be identified, in a…

High-resolution mass spectra of helium droplets doped with C$_{60}$ and formic acid (FA) are ionized by electrons. Positive ion mass spectra reveal cluster ions [(C$_{60}$)$_p$FA$_n$]$^+$ together with their hydrogenated and dehydrogenated…

Atomic and Molecular Clusters · Physics 2022-11-21 Masoomeh Mahmoodi-Darian , Elias Jabbour Al Maalouf , Samuel Zöttl , Paul Scheier , Olof Echt

Helium (He) nanodroplets irradiated by intense near-infrared laser pulses form a nanoplasma by avalanche-like electron impact ionizations even at lower laser intensities where He is not directly field ionized, provided that the droplets…

Atomic and Molecular Clusters · Physics 2017-12-06 Andreas Heidenreich , Dominik Schomas , Marcel Mudrich

The real-time dynamics of photoexcited and photoionized rubidium (Rb) atoms attached to helium (He) nanodroplets is studied by femtosecond pump-probe mass spectrometry. While excited Rb atoms in the perturbed 6p-state (Rb*) desorb off the…

Atomic and Molecular Clusters · Physics 2020-11-09 J. von Vangerow , O. John , andF. Stienkemeier , M. Mudrich

We have investigated the formation of helium droplets in two physical situations. In the first one, droplets are atomised from superfluid or normal liquid by a fast helium vapour flow. In the second, droplets of normal liquid are formed…

Soft Condensed Matter · Physics 2009-11-13 Pierre-Etienne Wolf , Fabien Bonnet , Sylvain Perraud , Laurent Puech , Bernard Rousset , Pierre Thibault

The local order around alkali (Li$^+$ and Na$^+$) and alkaline-eath (Be$^+$, Mg$^+$ and Ca$^+$) ions in $^4$He clusters has been studied using ground-state path integral Monte Carlo calculations. We apply a criterion based on multipole…

Other Condensed Matter · Physics 2007-05-23 Stefano Paolini , Francesco Ancilotto , Flavio Toigo