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The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic field on rough metal surfaces are considered. It is…

Optics · Physics 2014-11-17 V. P. Chelibanov , A. M. Polubotko

We present a general model study of surface-enhanced resonant Raman scattering and fluorescence focusing on the interplay between electromagnetic effects and the molecular dynamics. Our model molecule is placed close to two Ag…

Other Condensed Matter · Physics 2007-05-23 Hongxing Xu , Xue-Hua Wang , Martin P. Persson , H. Q. Xu , Mikael Kall , Peter Johansson

In this paper we explored the scattering behavior of thin cylinders made of LHM and coated by a monoatomic graphene layer. A spectral tunability of the resonance peaks is evidenced by altering the chemical potential of the graphene coating,…

A typical surface-enhanced Raman scattering (SERS) system relies on deeply subwavelength field localization in nanoscale plasmonic cavities to enhance both the excitation and emission of Raman-active molecules. Here, we demonstrate that a…

Quantum Physics · Physics 2025-05-27 Mikolaj K. Schmidt , Alexander A. High , Michael J. Steel

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

Raman lasers based on integrated silica whispering gallery mode resonant cavities have enabled numerous applications from telecommunications to biodetection. To overcome the intrinsically low Raman gain value of silica, these devices…

Optics · Physics 2020-01-06 Hyungwoo Choi , Dongyu Chen , Fan Du , Rene Zeto , Andrea M Armani

We study scattering by metamaterials with negative indices of refraction, which are known to support \emph{surface plasmons} -- long-lived states that are highly localized at the boundary of the cavity. This type of states has found uses in…

Spectral Theory · Mathematics 2025-05-29 Yan-Long Fang , Jeffrey Galkowski

Phonon-polaritons propagating in crystal volume offer the possibility of transferring information throughout matter (via phonons) at high (photon-like) velocity and tunable frequency/wavelength in the far-infrared. However, from the…

Optics · Physics 2025-09-03 Mayssoune Mina , Toni Alhaddad , Olivier Pagès

Metastable qubits in atomic systems can enable large-scale quantum computing by simplifying hardware requirements and adding efficient erasure conversion to the pre-existing toolbox of high-fidelity laser-based control. For trapped atomic…

Near-field enhanced, nano-Raman spectroscopy has been successfully used to probe the surface chemistry of silicon prepared using standard wafer cleaning and processing techniques. The results demonstrate the utility of this measurement for…

Materials Science · Physics 2010-02-16 P. G. Spizzirri , J. -H. Fang , S. Rubanov , E. Gauja , S. Prawer

We investigate theoretically the optical properties associated to plasmon resonances of metal nanowires with cross section given by low-order Chebyshev nanoparticles (like rounded-tip nanostars or nanoflowers). The impact of the nanoflower…

Optics · Physics 2009-10-23 V. Giannini , R. Rodriguez-Oliveros , J. A. Sanchez-Gil

The interaction between electromagnetic waves and objects is strongly affected by the shape and material composition of the latter. Artificially created materials, formed by a subwavelength structuring of their unit cells, namely…

Classical Physics · Physics 2018-02-07 Dmitry Filonov , Andrey Shmidt , Amir Boag , Pavel Ginzburg

We show that spontaneous Raman scattering of incident radiation can be observed in cavity-QED systems without external enhancement or coupling to any vibrational degree of freedom. Raman scattering processes can be evidenced as resonances…

An internal field induced resonant intensity enhancement of Raman scattering of phonon excitations in InAs nanowires is reported. The experimental observation is in good agreement with the simulated results for the scattering of light under…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Jaya Kumar Panda , Anushree Roy , Achintya Singha , Mauro Gemmi , Daniele Ercolani , Vittorio Pellegrini , Lucia Sorba

The surface-enhanced Raman scattering in graphene deposited on AlxGa1-xN/GaN axial heterostructure nanowires was investigated. The intensity of graphene Raman spectra was found not to be correlated with aluminium content. Analysis of…

In the context of the quantum-mechanical description of single-molecule surface-enhanced Raman scattering, intensity-field correlation measurements of photons emitted from a plasmonic cavity are explored, theoretically, using the technique…

Quantum Physics · Physics 2019-07-10 Octavio de los Santos Sánchez

Highly ordered periodic arrays of silver nanoparticles have been fabricated which exhibit surface plasmon resonances in the visible spectrum. We demonstrate the ability of these structures to alter the fluorescence properties of vicinal dye…

Other Condensed Matter · Physics 2009-11-13 Nic Cade , Tom Ritman-Meer , David Richards

A combined scattering mechanism involving the states of free electron-hole pairs (exciton continuum) and discrete excitons as intermediate states in the multi-phonon Raman scattering leads to (1) a strong increase of the scattering…

Condensed Matter · Physics 2009-10-28 I. G. Lang , A. V. Prokhorov , M. Cardona , V. I. Belitsky , A. Cantarero , S. T. Pavlov

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

A theoretical model of resonant hyper-Raman scattering by an ensemble of spherical semiconductor quantum dots has been developed. The electronic intermediate states are described as Wannier-Mott excitons in the framework of the envelope…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 E. Menendez-Proupin , C. Trallero-Giner , A. Garcia-Cristobal