Related papers: Colloidal charge reversal: Dependence on the ionic…
We present an exact field-theoretic formulation for a fluctuating, generally asymmetric, salt density in the presence of a charged plate. The non-linear Poisson-Boltzmann equation is obtained as the saddle-point of our field theory action.…
Recent experiments report that slowly-sheared noncolloidal particle suspensions can exhibit unexpected rate($\omega$)-dependent complex viscosities in oscillatory shear, despite a constant relative viscosity in steady shear. Using a minimal…
Through molecular dynamics simulations considering thermal vibration of surface atoms, ionic behaviors in concentrated NaCl solutions confined between discretely charged silicon surfaces have been investigated. The electric double layer…
Charged colloidal dispersions make up the basis of a broad range of industrial and commercial products, from paints to coatings and additives in cosmetics. During drying, an initially liquid dispersion of such particles is slowly…
Electron microdiffraction study of phase transition in La2/3Ca1/3MnO3 revealed temperature dependent (h+1/2,0,l) diffraction spots. Their intensity peaks at Tc. Quantitative electron diffraction intensity analysis shows that they come from…
Through studying the critical phenomena in continuum-percolation of discs, we find a new approach to locate the critical point, i.e. using the inflection point of $P_\infty$ as an evaluation of the percolation threshold. The susceptibility,…
Complexation of a long flexible polyelectrolyte (PE) molecule with oppositely charged spherical particles such as colloids, micelles, or globular proteins in a salty water solution is studied. PE binds spheres winding around them, while…
We study charge regulation of colloidal particles inside aqueous electrolyte solutions. To stabilize colloidal suspension against precipitation, colloidal particles are synthesized with either acidic or basic groups on their surface. In…
When a fluid that undergoes a vapor to liquid transition in the bulk is confined to a long cylindrical pore, the phase transition is shifted (mostly due to surface effects at the walls of the pore) and rounded (due to finite size effects).…
Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…
In bootstrap percolation it is known that the critical percolation threshold tends to converge slowly to zero with increasing system size, or, inversely, the critical size diverges fast when the percolation probability goes to zero. To…
The mean volume reflection angle of a high-energy charged particle passing through a bent crystal is expressed as an integral involving the effective interplanar potential over a single crystal period. Implications for positively and…
The scaling of the AC conductivity in quantum critical holographic theories at finite density, finite temperature and in the presence of momentum dissipation is considered. It is shown that there is generically an intermediate window of…
We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. Molecular dynamics (MD) simulations are used to elucidate the effect of $discrete$ macroion charge distribution on…
The venerable theory of electrokinetic phenomena rests on the hypothesis of a dilute solution of point-like ions near a weakly charged surface, whose potential relative to the bulk is of order the thermal voltage ($kT/e \approx 25$ mV at…
Effect of an oscillatory decay of the charge density in concentrated ionic solutions and ionic liquids on the double-layer capacitance is studied in a framework of a mesoscopic theory. Only Coulomb and steric forces between the ions that…
We develop a thermodynamic description of particles held at a fixed surface potential. This system is of particular interest in view of the continuing controversy over the possibility of a fluid-fluid phase separation in aqueous colloidal…
Charge reversal of the planar electrical double layer is studied by means of a well known integral equations theory. By a numerical analysis, a diagram is constructed with the onset points of charge reversal in the space of the fundamental…
The properties of a fluid, or Ising magnet, confined in a $L \times \infty$ geometry with opposing surface fields at the walls are studied by density matrix renormalization techniques. In particular we focus on the effect of gravity on the…
In spite of their enormous applications as alternative energy storage devices and lubricants, room temperature ionic liquids (ILs) still pose many challenges from a pure scientific view point. We develop an IL microscopic theory in terms of…