English

Critical point shift in a fluid confined between opposing walls

Statistical Mechanics 2009-10-30 v2

Abstract

The properties of a fluid, or Ising magnet, confined in a L×L \times \infty geometry with opposing surface fields at the walls are studied by density matrix renormalization techniques. In particular we focus on the effect of gravity on the system, which is modeled by a bulk field whose strength varies linearly with the distance from the walls. It is well known that in the absence of gravity phase coexistence is restricted to temperatures below the wetting temperature. We find that gravity restores phase coexistence up to the bulk critical temperature, in agreement with previous mean field results. A detailed study of the scaling to the critical point, as LL \to \infty, is performed. The temperature shift scales as 1/LyT1/L^{y_T}, while the gravitational constant scales as 1/L1+yH1/L^{1+y_H}, with yTy_T and yHy_H the bulk thermal and magnetic exponents respectively. For weak surface fields and LL not too large, we also observe a regime where the gravitational constant scales as 1/L1+yHΔ1yT1/L^{1+y_H - \Delta_1 y_T} (Δ1\Delta_1 is the surface gap exponent) with a crossover, for sufficiently large LL, to a scaling of type 1/L1+yH1/L^{1+y_H}.

Keywords

Cite

@article{arxiv.cond-mat/9709176,
  title  = {Critical point shift in a fluid confined between opposing walls},
  author = {Enrico Carlon and Andrzej Drzewinski},
  journal= {arXiv preprint arXiv:cond-mat/9709176},
  year   = {2009}
}

Comments

9 pages, RevTeX, 11 PostScript figures included. Minor corrections. Final version as published