Interplay of complete wetting, critical adsorption, and capillary condensation
Abstract
The excess adsorption in two-dimensional Ising strips subject to identical boundary fields, at both one-dimensional surfaces decaying in the orthogonal direction as , is studied for various values of and along various thermodynamic paths below the critical point by means of the density-matrix renormalization-group method. The crossover behavior between the complete wetting and critical adsorption regimes, occurring in semi-infinite systems, are strongly influenced by confinement effects. Along isotherms the asymptotic power law dependences on the external bulk field, which characterize these two regimes, are undercut by capillary condensation. Along the pseudo first-order phase coexistence line of the strips, which varies with temperature, we find a broad crossover regime where both the thickness of the wetting film and increase as function of the reduced temperature but do not follow any power law. Above the wetting temperature the order parameter profiles are not slab-like but exhibit wide interfacial variations and pronounced tails. Inter alia, our explicit calculations demonstrate that, contrary to opposite claims by Kroll and Lipowsky [Phys. Rev. B {\bf 28}, 5273 (1983)], for critical wetting transitions do exist and we determine the corresponding wetting phase diagram in the plane.
Keywords
Cite
@article{arxiv.0808.2966,
title = {Interplay of complete wetting, critical adsorption, and capillary condensation},
author = {A. Drzewinski and A. Maciolek and A. Barasinski and S. Dietrich},
journal= {arXiv preprint arXiv:0808.2966},
year = {2015}
}
Comments
RevTeX 23 Pages and 17 figures, submitted to Phys. Rev. E