Related papers: Efficient formation of deeply bound ultracold mole…
We have demonstrated a new, accessible and economical technique, dubbed photostop, for producing high densities of trappable molecules. Direct measurements are presented of NO molecules produced with a narrow velocity distribution centered…
We spectroscopically investigate the hyperfine, rotational and Zeeman structure of the vibrational levels $\text{v}'=0$, $7$, $13$ within the electronically excited $c^3\Sigma_g^+$ state of $^{87}\text{Rb}_2$ for magnetic fields of up to…
We employ collisions of individual atomic cesium (Cs) impurities with an ultracold rubidium (Rb) gas to probe atomic interaction with hyperfine- and Zeeman-state sensitivity. Controlling the Rb bath's internal state yields access to novel…
A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…
Broadband spectroscopic observations with high sensitivity provide an unbiased way to detect emissions of molecules in space. We present deep observations from ~ 105.8 GHz to 113.6 GHz toward 50 Galactic massive star-forming regions using…
We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
We demonstrate the occurrence of oscillatory reactions in the ultra-cold chemistry of atom-molecular Bose-Einstein condensate. Nonlinear oscillations in the mean-field dynamics occur for a specific range of elliptic modulus, giving rise to…
Ultra-cold sodium molecules were produced from an atomic Bose-Einstein condensate by ramping an applied magnetic field across a Feshbach resonance. More than $10^5$ molecules were generated with a conversion efficiency of $\sim$4%. Using…
Chemical reactions at ultracold temperatures are expected to be dominated by quantum mechanical effects. Although progress towards ultracold chemistry has been made through atomic photoassociation, Feshbach resonances and bimolecular…
The formation of molecules and supramolecular structures results from bonding by conservative forces acting among electrons and nuclei and giving rise to equilibrium configurations defined by minima of the interaction potential. Here we…
We explore the scattering properties of ultracold ground-state Cs atoms at magnetic fields between 450 G (45 mT) and 1000 G. We identify 17 new Feshbach resonances, including two very broad ones near 549 G and 787 G. We measure the binding…
Photoassociation of ultracold atoms induced by chirped picosecond pulses is analyzed in a non-perturbative treatment by following the wavepackets dynamics on the ground and excited surfaces. The initial state is described by a Boltzmann…
Regular pattern formation is ubiquitous in nature; it occurs in biological, physical, and materials science systems. Here we propose a set of experiments with ultracold atoms that show how to examine different types of pattern formation. In…
We report on the creation of $^{86}$Sr$_2$ molecules in the halo state and neighboring weakly bound states. Efficient molecule production via one-photon photoassociation relies on sufficient wavefunction overlap between the target…
We propose a new approach to excite ion-pair states of ultracold dimers. The central idea is a two-step process where first long-range Rydberg molecules are formed by photoassociation, which are then driven by stimulated emission towards…
Collision cross sections and rate constants between two ground- state oxygen molecules are investigated theoretically at translational energies below $\sim 1$K and in zero magnetic field. We present calculations for elastic and spin-…
One of the explanations for the recent EDGES-LOW band 21-cm measurements of a strong absorption signal around 80~MHz is the presence of an excess radio background to the Cosmic Microwave Background (CMB). Such excess can be produced by the…
We study the rovibronic transitions in NaK$_2$ between its electronic ground state $1^2A'$ and its second excited state $3^2A'$, to identify possible pathways for the creation of ultracold ground-state triatomic molecules. Our methodology…
An experimental pump-probe study of the photoassociative creation of translationally ultracold rubidium molecules is presented together with numerical simulations of the process. The formation of loosely bound excited-state dimers is…