Related papers: Laser Induced Selective Alignment of Water Spin Is…
Water exists as two nuclear-spin isomers, para and ortho, determined by the overall spin of its two hydrogen nuclei. For isolated water molecules the conversion between these isomers is forbidden and they act as different molecular species.…
Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…
A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…
We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…
We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…
We theoretically analyze the effectiveness of multiple-pulse laser alignment methods for asymmetric-top molecules. As an example, we choose SO_2 and investigate the alignment dynamics induced by two different sequences, each consisting of…
We show that field-free molecular orientation induced by a half-cycle pulse may be considerably enhanced by an additional laser pulse inducing molecular anti-alignment. Two qualitatively different enhancement mechanisms are identified…
Spin degrees of freedom of water molecule in gas and liquid state were investigated in order to provide a reasonable answer about the unsolved problem of a long-term behavior of water spin isomers. The approach used involves an assumption…
Several laser techniques have been suggested and demonstrated recently for preparing polarizable molecules in rapidly spinning states with a disc-like angular distribution. We consider motion of these spinning discs in inhomogeneous fields,…
Strong quasi-adiabatic laser alignment of the indole-water-dimer clusters, an amino-acid chromophore bound to a single water molecule through a hydrogen bond, was experimentally realized. The alignment was visualized through ion and…
A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest lying rotational…
We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…
Laser-induced alignment of particles and molecules was long envisioned to support three-dimensional structure determination using "single-molecule diffraction" with x-ray free-electron lasers [PRL 92, 198102 (2004)]. However, the alignment…
It has been known for quite some time that spinning polygon, and similar, swept lasers used in OCT favor the short to long wavelength sweep direction because of four wave mixing in the gain medium. Here we have reformulated the problem in…
This paper presents a comprehensive exposition of a spontaneous laser model for a resonant semi-classical system of radiation and ion cluster-solvated rotating water molecules, which have subtly variable moments of inertia. In this system,…
Water exists in two forms, para and ortho, that have nuclear spin states with different symmetries. Here we report the conversion of fullerene-encapsulated para-water to ortho-water. The enrichment of para-water at low temperatures is…
We report on a new phenomenon of molecular nuclear spin isomers conversion in the field of resonant laser radiation. It is based on the isomer-selective optical excitation and the difference of conversion rates for excited and unexcited…
In recent years it became possible to align molecules in free space using ultrashort laser pulses. Here we explore two schemes for controlling molecule-surface scattering process, which are based on the laser-induced molecular alignment. In…
Ionization and excitation of water molecules in intense laser pulses is studied theoretically by solving the three-dimensional time-dependent electronic Schr\"odinger equation within the single-active-electron approximation. The possibility…
An all-optical method of ultrafast spin rotation is put forward to precisely manipulate the polarization of relativistic charged particle beams of leptons or ions. In particular, laser-driven dense ultrashort beams are manipulated via…