Related papers: Growth mechanisms of vapor-born polymer films
The morphological scaling properties of linear polymer films grown by vapor deposition polymerization (VDP) are studied by 1+1D Monte Carlo simulations. The model implements the basic processes of random angle ballistic deposition ($F$),…
As a first step to understand anomalous kinetic roughening with multifractality in recent experiments of the vapor deposition polymerization (VDP) growth, we study a simple toy model of the VDP growth in a (1+1)-dimensional lattice, along…
In many growth processes particles are highly mobile in an active layer at the surface, but are relatively immobile once incorporated in the bulk. We study models in which atoms are allowed to interact, equilibrate, and order on the…
The dynamic scaling of mesoscopically thick films (up to $10^{4}$ atomic layers) grown with the Clarke-Vvedensky model is investigated numerically for broad ranges of values of the diffusion-to-deposition ratio $R$ and lateral neighbor…
The structural aspects of polyacrylamide thin films annealed at degradation threshold temperature have been studied as a function of annealing time using in situ X-ray reflectivity technique in vacuum. We observe significant decrease of…
We study the interplay between surface roughening and phase separation during the growth of binary films. Renormalization group calculations are performed on a pair of equations coupling the interface height and order parameter…
Polymer association at liquid-liquid interfaces is a promising way to spontaneously obtain soft self-healing membranes. In the case of reversible bonding between two polymers, the macromolecules are mobile everywhere within the membrane and…
Monte Carlo simulations are employed to investigate the surface growth generated by deposition of particles of different sizes on a substrate, in one and two dimensions. The particles have a linear form, and occupy an integer number of…
We study the interplay between surface roughening and phase separation during the growth of binary films. Already in 1+1 dimension, we find a variety of different scaling behaviors depending on how the two phenomena are coupled. In the most…
Thin film deposition on weakly interacting substrates exhibits a unique growth mode characterized by initially strong island formation and rapidly increasing roughness, which reaches a maximum and subsequently decreases as the film returns…
We study the temporal growth pattern of surface fluctuations on a series of spinodally unstable polymer films where the degree of instability is controlled by the film thickness. For films in the deep spinodal region, the growth rate…
We present some results of Monte Carlo simulations for the deposition of particles of different sizes on a two-dimensional substrate. The particles are linear, height one, and can be deposited randomly only in the two, $x$ and $y$…
Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on…
We study the local and global roughness scaling in growth models with grains at the film surfaces. The local roughness, measured as a function of window size r, shows a crossover at a characteristic length r_c, from a rapid increase with…
Using self-consistent field and density-functional theories, we first investigate colloidal self-assembling of colloid/polymer films confined between two soft surfaces grafted by polymers. With the increase of colloidal concentrations, the…
A computer simulation model is proposed to study film growth and surface roughness in aqueous ($A$) solution of hydrophobic ($H$) and hydrophilic ($P$) groups on a simple three dimensional lattice of size $L_x \times L_y \times L_z$ with an…
We report molecular dynamics simulation results on the equilibrium properties of polymer thin films adsorbed onto flat and curved substrates. We first systematically determine the contact angle of polymer droplets on flat substrates as a…
Growth of Co film on SiO2 substrates with the surface roughness of 0.5 nm and 1.6 nm has been studied in situ using the magneto-optical Kerr effect (MOKE) and four probe resistivity measurements. In-situ measurements jointly suggest the…
The shear rate dependence of the slip length in thin polymer films confined between atomically flat surfaces is investigated by molecular dynamics simulations. The polymer melt is described by the bead-spring model of linear flexible…
The properties of artificially grown thin films are strongly affected by surface processes during growth. Coherent X-rays provide an approach to better understand such processes and fluctuations far from equilibrium. Here we report results…