English

Dewetting of thin polymer films near the glass transition

Soft Condensed Matter 2009-11-07 v4

Abstract

Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on the shear-thinning behaviour of these films. We analyse the profile of the dewetting film, and characterize the time evolution of the dry region radius, Rd(t)R_{d}(t), and of the rim height, hm(t)h_{m}(t). After a transient time depending on the initial thickness, hm(t)h_{m}(t) grows like t\sqrt{t} while Rd(t)R_{d}(t) increases like exp(t)\exp{(\sqrt{t})}. Different regimes of growth are expected, depending on the initial film thickness and experimental time range.

Keywords

Cite

@article{arxiv.cond-mat/0201528,
  title  = {Dewetting of thin polymer films near the glass transition},
  author = {F. Saulnier and E. Raphael and P. -G. de Gennes},
  journal= {arXiv preprint arXiv:cond-mat/0201528},
  year   = {2009}
}

Comments

4 pages, 5 figures Revised version, published in Physical Review Letters: F. Saulnier, E. Raphael and P.-G. de Gennes, Phys. Rev. Lett. 88, 196101 (2002)