Dewetting of thin polymer films near the glass transition
Abstract
Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on the shear-thinning behaviour of these films. We analyse the profile of the dewetting film, and characterize the time evolution of the dry region radius, , and of the rim height, . After a transient time depending on the initial thickness, grows like while increases like . Different regimes of growth are expected, depending on the initial film thickness and experimental time range.
Cite
@article{arxiv.cond-mat/0201528,
title = {Dewetting of thin polymer films near the glass transition},
author = {F. Saulnier and E. Raphael and P. -G. de Gennes},
journal= {arXiv preprint arXiv:cond-mat/0201528},
year = {2009}
}
Comments
4 pages, 5 figures Revised version, published in Physical Review Letters: F. Saulnier, E. Raphael and P.-G. de Gennes, Phys. Rev. Lett. 88, 196101 (2002)