Related papers: Decrease of Entropy and Chemical Reactions
A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…
If a macroscopic (random) classical system is put into a random state in phase space, it will of course the most likely have an almost maximal entropy according to second law of thermodynamics. We will show, however, the following theorem:…
A pair of symmetric expressions for the second law of thermodynamics is put forward. The conservation and transfer of entropy is discussed and applied to problems like biology, culture and life itself. A new explanation is given to the…
Starting from second order around thermal equilibrium, the response of a statistical mechanical system to an external stimulus is not only governed by dissipation and depends explicitly on dynamical details of the system. The so called…
The second law of thermodynamics is a statement about the statistics of the entropy production, $\langle \Sigma \rangle \geq 0$. For small systems, it is known that the entropy production is a random variable and negative values ($\Sigma <…
We study self-organisation of collective motion as a thermodynamic phenomenon, in the context of the first law of thermodynamics. It is expected that the coherent ordered motion typically self-organises in the presence of changes in the…
Particle motion at the micro-scale is an incessant tug-of-war between thermal fluctuations and applied forces on one side, and the strong resistance exerted by fluid viscosity on the other. Friction is so strong that completely neglecting…
To study the dynamics of chemical processes, we often adopt rate equations to observe the change in chemical concentrations. However, when the number of the molecules is small, the fluctuations cannot be neglected. We often study the…
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
The Second Law of Thermodynamics states that the entropy of a closed system is non-decreasing. Discussing the Second Law in the quantum world poses new challenges and provides new opportunities, involving fundamental…
The entropy production occurring in relativistic hydrodynamical systems such as the quark-gluon plasma (QGP) formed in high-energy nuclear collisions is explored. We study mechanisms which change the composition of the fluid, i.e. particle…
Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create inhomogeneities that…
Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…
Traditional form of the second law of thermodynamics is strongly restricted by three conditions: One is the initial joint state of the system and surroundings should be a product state, so that there exists no initial correlations. The…
Events in mesoscopic systems often take place at first-passage times, as is for instance the case for a colloidal particle that escapes a metastable state. An interesting question is how much work an external agent has done on a particle…
The reversibility and recurrence paradoxes are key issues that have been left unsolved in researches on the foundation of thermodynamics since the 19th century. This article shows that (1) the reversibility paradox can be overcome if we pay…
Living systems maintain or increase local order by working against the Second Law of Thermodynamics. Thermodynamic consistency is restored as they dissipate heat, thereby increasing the net entropy of their environment. Recently introduced…
For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…
A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…
For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy ($S_{a}$) always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics ($S_{a}\geq0$). Here…