Entropy variation rate divided by temperature always decreases
Abstract
For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy () always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics (). Here we analytically prove that, unlike the entropy itself, the entropy variation rate () defies the monotonicity for multiple reservoirs (). In other words, there always exist minima. For example, when a system is heated by two reservoirs from initially to at the final steady state, decreases steadily first. Then suddenly it turns around and starts to increases at until it reaches its steady-state value, exhibiting peculiar dipping behaviors. In addition, the crux of our work is the proof that a newly-defined variable, , always decreases. Our proof involves the Newton's law of cooling, in which the heat transfer coefficient is assumed to be constant. These theoretical macro-scale findings are validated by numerical experiments using the Crank-Nicholson method, and are illustrated with practical examples. They constitute an alternative to the traditional second-law statement, and may provide useful references for the future micro-scale entropy-related research.
Cite
@article{arxiv.1410.5195,
title = {Entropy variation rate divided by temperature always decreases},
author = {T. M. Shih and Z. J. Gao and H. Merlitz and L. Rondoni and P. J. Pagni and Z. Chen},
journal= {arXiv preprint arXiv:1410.5195},
year = {2014}
}
Comments
11 pages, 12 figures