English

Entropy variation rate divided by temperature always decreases

Computational Physics 2014-10-22 v2

Abstract

For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy (SaS_{a}) always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics (Sa0S_{a}\geq0). Here we analytically prove that, unlike the entropy itself, the entropy variation rate (B=dSa/dtB=dS_{a}/dt) defies the monotonicity for multiple reservoirs (n2n\geq2). In other words, there always exist minima. For example, when a system is heated by two reservoirs from T=300KT=300\,K initially to T=400KT=400\,K at the final steady state, BB decreases steadily first. Then suddenly it turns around and starts to increases at 387K387\,K until it reaches its steady-state value, exhibiting peculiar dipping behaviors. In addition, the crux of our work is the proof that a newly-defined variable, B/TB/T, always decreases. Our proof involves the Newton's law of cooling, in which the heat transfer coefficient is assumed to be constant. These theoretical macro-scale findings are validated by numerical experiments using the Crank-Nicholson method, and are illustrated with practical examples. They constitute an alternative to the traditional second-law statement, and may provide useful references for the future micro-scale entropy-related research.

Keywords

Cite

@article{arxiv.1410.5195,
  title  = {Entropy variation rate divided by temperature always decreases},
  author = {T. M. Shih and Z. J. Gao and H. Merlitz and L. Rondoni and P. J. Pagni and Z. Chen},
  journal= {arXiv preprint arXiv:1410.5195},
  year   = {2014}
}

Comments

11 pages, 12 figures

R2 v1 2026-06-22T06:29:11.273Z