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Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…

Solar and Stellar Astrophysics · Physics 2017-08-23 S. Ioppolo , H. M. Cuppen , C. Romanzin , E. F. van Dishoeck , H. Linnartz

Water is abundantly present in the Universe. It is the main component of interstellar ice mantles and a key ingredient for life. Water in space is mainly formed through surface reactions. Three formation routes have been proposed in the…

Solar and Stellar Astrophysics · Physics 2017-08-23 H. M. Cuppen , S. Ioppolo , C. Romanzin , H. Linnartz

The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…

Astrophysics of Galaxies · Physics 2014-10-22 Thanja Lamberts , Herma Cuppen , Gleb Fedoseev , Sergio Ioppolo , Ko-Ju Chuang , Harold Linnartz

The reactions of cold H atoms with solid O2 molecules were investigated at 10 K. The formation of H2O2 and H2O has been confirmed by in-situ infrared spectroscopy. We found that the reaction proceeds very efficiently and obtained the…

Astrophysics · Physics 2009-11-13 N. Miyauchi , H. Hidaka , T. Chigai , A. Nagaoka , N. Watanabe , A. Kouchi

Context. The synthesis of water is one necessary step in the origin and development of life. It is believed that pristine water is formed and grows on the surface of icy dust grains in dark interstellar clouds. Until now, there has been no…

Instrumentation and Methods for Astrophysics · Physics 2015-05-13 F. Dulieu , L. Amiaud , E. Congiu , J-H. Fillion , E. Matar , A. Momeni , V. Pirronello , J. L. Lemaire

Water is observed throughout the universe, from diffuse interstellar clouds to protoplanetary disks around young stars, and from comets in our own solar system and exoplanetary atmospheres to galaxies at high redshifts. This review…

Astrophysics of Galaxies · Physics 2013-12-18 Ewine F. van Dishoeck , Eric Herbst , David A. Neufeld

The synthesis of water is one necessary step in the origin and development of life. It is believed that pristine water is formed and grows on the surface of icy dust grains in dark interstellar clouds. Until now, there has been no…

Solar and Stellar Astrophysics · Physics 2009-11-12 F. Dulieu , L. Amiaud , J-H. Fillion , E. Matar , A. Momeni , V. Pirronello , J. L. Lemaire

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by…

Solar and Stellar Astrophysics · Physics 2015-05-19 S. Cazaux , V. Cobut , M. Marseille , M. Spaans , P. Caselli

A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The model predicts the existence of a…

Astrophysics · Physics 2009-11-13 Renaud Papoular

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…

Chemical Physics · Physics 2015-06-17 Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck , Geert-Jan Kroes

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most…

The formation of water molecules from the reaction between ozone (O3) and D-atoms is studied experimentally for the first time. Ozone is deposited on non-porous amorphous solid water ice (H2O), and D-atoms are then sent onto the sample held…

Astrophysics of Galaxies · Physics 2015-05-13 H. Mokrane , H. Chaabouni , M. Accolla , E. Congiu , F. Dulieu , M. Chehrouri , J. L. Lemaire

CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between…

Astrophysics of Galaxies · Physics 2023-09-06 Germán Molpeceres , Joan Enrique-Romero , Yuri Aikawa

Interstellar ices are mainly composed of amorphous solid water (ASW) containing small amounts of hypervolatiles, such as O2, whose diffusion-limited reactions play a key role in space chemistry. Although O2 is an important precursor…

Astrophysics of Galaxies · Physics 2026-03-13 Lina Coulaud , Julia C. Santos , Ko-Ju Chuang

Water is an important reservoir species for oxygen in interstellar space and plays a key role in the physics of star formation through cooling by far-infrared emission. Whilst water vapour is present at high abundances in the outflows of…

Astrophysics of Galaxies · Physics 2013-08-20 Kevin Hickson , Jean-Christophe Loison , Philippe Caubet

Hydroxylamine (NH2OH) is one of the potential precursors of complex pre-biotic species in space. Here we present a detailed experimental study of hydroxylamine formation through nitric oxide (NO) surface hydrogenation for astronomically…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Sergio Ioppolo , Thanja Lamberts , Junfeng Zhen , Herma M. Cuppen , Harold Linnartz

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

Molecular hydrogen is the most abundant molecular species in the Universe. While no doubts exist that it is mainly formed on the interstellar dust grain surfaces, many details of this process remain poorly known. In this work, we focus on…

The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the…

Astrophysics · Physics 2009-11-10 F. A. van Broekhuizen , J. V. Keane , W. A. Schutte
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