Related papers: Laboratory evidence for efficient water formation …
This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…
A recent suggestion that acetamide, \ce{CH3C(O)NH2}, could be readily formed on water-ice grains by the acid induced addition of water across the \ce{CN} bond is now shown to be valid. Computational modelling of the reaction between…
Understanding the formation of molecules under conditions relevant to interstellar chemistry is fundamental to characterize the chemical evolution of the universe. Using reactive molecular dynamics simulations with model-based or…
Dimethyl ether is one of the most abundant interstellar complex organic molecules. Yet its formation route remains elusive. In this work, we have performed electronic structure and kinetics calculations to derive the rate coefficients for…
Context. There are only six molecules containing N-O bond that are detected in gaseous phase in interstellar medium. One of those is nitrous oxide (N2O), which was searched for but not found in solid form from as early as Infrared Space…
The study of warm molecular gas in the inner regions of protoplanetary disks is of key importance for the study of planet formation and especially for the transport of H2O and organic molecules to the surfaces of rocky planets/satellites.…
We investigated the behavior of H$_2$, main constituent of the gas phase in dense clouds, after collision with amorphous solid water (ASW) surfaces, one of the most abundant chemical species of interstellar ices. We developed a general…
In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…
The detection of ozone (O3) in the surface ices of Ganymede, Jupiters largest moon, and of the Saturnian moons Rhea and Dione, has motivated several studies on the route of formation of this species. Previous studies have successfully…
We re-examine the constraints provided by Herschel Space Observatory data regarding cold water emission from protoplanetary disks. Previous disk models that were used to interpret observed water emission concluded that oxygen (O/H) is…
The first off-lattice Monte Carlo kinetics model of interstellar dust-grain surface chemistry is presented. The positions of all surface particles are determined explicitly, according to the local potential minima resulting from the…
(Abridged) The water deuterium fractionation (HDO/H$_2$O abundance ratio) has traditionally been used to infer the amount of water brought to Earth by comets. Measuring this ratio in deeply-embedded low-mass protostars makes it possible to…
Molecular outflows contributing to the matter cycle of star forming galaxies are now observed in small and large systems at low and high redshift. Their physical origin is still unclear. In most theoretical studies only warm ionised/neutral…
Context: In the laboratory, hydrogen peroxide (HOOH) was proven to be an intermediate product in the solid-state reaction scheme that leads to the formation of water on icy dust grains. When HOOH desorbs from the icy grains, it can be…
The build-up of galaxies is regulated by a complex interplay between gravitational collapse, galaxy merging and feedback related to AGN and star formation. The energy released by these processes has to dissipate for gas to cool, condense,…
Cold cores in interstellar molecular clouds represent the very first phase in star formation. The physical conditions of these objects are studied in order to understand how molecular clouds evolve and how stellar masses are determined. The…
We report on laboratory measurements of molecular hydrogen formation and recombination on an olivine slab as a function of surface temperature under conditions relevant to those encountered in the interstellar medium. On the basis of our…
We have used a coupled dynamical and chemical model to examine the chemical changes induced by the passage of an interstellar shock in well shielded regions. Using this model we demonstrate that the formation of water in a shock will be…
The origin of Earth oceans is controversial. Earth could have acquired its water either from hydrated silicates (wet Earth scenario) or from comets (dry Earth scenario). [HDO]/[H2O] ratios are used to discriminate between the scenarios.…
The abundance of interstellar ice constituents is usually expressed with respect to the water ice because, in denser regions, a significant portion of the interstellar grain surface would be covered by water ice. The binding energy (BE), or…