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A complex magnetic order of the multiferroic compound Co3TeO6 has been revealed by neutron powder diffraction studies on ceramics and crushed single crystals. The compound adopts a monoclinic structure (s.g. C2/c) in the studied temperature…

Materials Science · Physics 2011-11-28 S. A. Ivanov , R. Tellgren , C. Ritter , P. Nordblad , R. Mathieu , G. Andre , N. V. Golubko , E. D. Politova , M. Weil

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite…

Double-perovskite A2BB'O6 oxides with magnetic B and B' ions and E*-type antiferromagnetic order (E*-AFM, i.e. the ++-- structure) are believed to exhibit promising multiferroic properties, and Y2CoMnO6 (YCMO) is one candidate in this…

Materials Science · Physics 2015-10-28 C. Y. Ma , S. Dong , P. X. Zhou , Z. Z. Du , M. F. Liu , H. M. Liu , Z. B. Yan , J. M. Liu

Interfacing complex oxides in atomically engineered layered structures can give rise to a wealth of exceptional electronic and magnetic properties that surpass those of the individual building blocks. Herein, we demonstrate a ferromagnetic…

Structural, impedance, ferroelectric and magnetic properties were examined in multiferroic Bi_{2}Fe_{4(1-x)}Co_{4x}O_{9} (0$\leq$x$\leq$0.02) ceramics synthesized via solid-state reaction method. X-ray diffraction analysis and Rietveld…

Materials Science · Physics 2016-05-06 S. R. Mohapatra , B. Sahu , M. Chandrasekhar , P. Kumar , S. D. Kaushik , S. Rath , A. K. Singh

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

Materials Science · Physics 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

We report on the magnetic structure and ordering of hexagonal LuFeO3 films grown by molecular-beam epitaxy (MBE) on YSZ (111) and Al2O3 (0001) substrates. Using a set of complementary probes including neutron diffraction, we find that the…

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

Double perovskite-based magnets wherein frustration and competition between emergent degrees of freedom are at play can lead to novel electronic and magnetic phenomena. Herein, we report the electronic structure and magnetic properties of…

A monoclinic phase was recently discovered near the morphotropic phase boundary in several high-performance piezoelectric perovskite solid solutions, but its properties have not been reported. In this paper the dielectric, piezo- and…

Materials Science · Physics 2016-08-31 A. A. Bokov , Z. -G. Ye

Solid solutions of (1-x)LaFeO3-(x)PbTiO3 (0<x<1) have been prepared by conventional solid-state reaction. These complex perovskites have been studied by means of X-ray (XRPD) and neutron powder (NPD) diffraction, complemented with…

Materials with coexisting and coupled ferroelectric and magnetic orders are rare. Here we show, using density functional theory calculations, that inducing Fe$_\mathrm{La}$ antisites into non-ferroelectric and antiferromagnetic LaFeO$_3$…

Materials Science · Physics 2025-08-13 Souren Majani , Harish K. Singh , Ulrich Aschauer

We report a first-principles study of Bi-based 3$d$-5$d$ ordered double perovskite oxides (A$_2$BB$^\prime$O$_6$) with a 3$d$ atom (Fe) at the B-site and 5$d$ atoms (Re,Ir) at the B$^\prime$-site while keeping highly polarizable ions…

Materials Science · Physics 2019-12-25 Paresh C. Rout , Varadharajan Srinivasan

Commencing from the centrosymmetric MnRMnSbO$_6$ compound, we explore the realm of magnetic polar double-double perovskite oxides characterized by significant ferroelectric polarization. Employing symmetry operations, first-principles…

Materials Science · Physics 2024-03-11 Monirul Shaikh , Duo Wang , Saurabh Ghosh

There are two interpretations offered for the different structural and magnetic properties of the mixed valence homo-metallic ludwigites, Co3O2BO3 and Fe3O2BO3. One of them associates the physical behavior to charge ordering processes among…

Materials Science · Physics 2019-05-20 M. Matos , J. Terra , D. E. Ellis

We investigate the electronic structure and the ferroelectric properties of the recently discovered multiferroic ScFeO$_3$ by means of ab-initio calculations. The $3d$ manifold of Fe in the half-filled configuration naturally favors an…

The combination of antiferroelectricity (AFE) and ferromagnetism (FM) in one structure would allow the development of new type of multiferroic candidates, which be applicable not only in magnetoelectric memories but also in novel energy…

Materials Science · Physics 2022-10-05 Cong-Cong Duan , Guo-Long Tan

Some of the Multiferroics [1] form a rare class of materials that exhibit magnetoelectric coupling arising from the coexistence of ferromagnetism and ferroelectricity, with potential for many technological applications.[2,3] Over the last…

Materials Science · Physics 2009-11-13 R. V. K. Mangalam , Nirat Ray , Umesh V. Waghmare , A. Sundaresan , C. N. R. Rao

Perovskite manganites with small A-site ions, as the first and canonical branch of type-II multiferroics, are ideal systems to exhibit magnetism-induced ferroelectricity. Despite their established magnetoelectric phase diagrams under low…

Materials Science · Physics 2026-01-15 Ming Yang , Jun Chen , Junfeng Wang , Chao Dong , Chengliang Lu , Gang Xu , Jinguang Cheng , Jianshi Zhou , Shuai Dong

We report the magnetic, dielectric and ferroelectric properties of polycrystalline iron vanadate(FeVO4), which has been recently found to exhibit multiferroicity in low temperature with noncollinear magnetic orderings. The influence of…

Materials Science · Physics 2011-02-21 L. Zhao , M. P. Y. Wu , K. W. Yeh , M. K. Wu
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