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In ABO3 perovskites, oxygen octahedron rotations are common structural distortions that can promote large ferroelectricity in BiFeO3 with an R3c structure [1], but suppress ferroelectricity in CaTiO3 with a Pbnm symmetry [2]. For many…

Materials Science · Physics 2016-04-05 Hongwei Wang , Jianguo Wen , Dean J. Miller , Qibin Zhou , Mohan Chen , Ho Nyung Lee , Karin M. Rabe , Xifan Wu

In this article, we perform the symmetry analysis of perovskite-based multiferroics: bismuth ferrite (BiFeO3)-like, orthochromites (RCrO3), and Ruddlesden-Popper perovskites (Ca3Mn2O7-like), being the typical representatives of…

Materials Science · Physics 2022-01-26 Zukhra Gareeva , Anatoly Zvezdin , Konstantin Zvezdin , Xiang Ming Chen

Using density functional calculations we explore the properties of as-yet-unsynthesized $3d - 5d$ ordered double perovskites ($A_2BB'$O$_6$) with highly polarizable Bi$^{3+}$ ions on the $A$ site. We find that the Bi$_2$NiReO$_6$ and…

Materials Science · Physics 2015-03-13 Marjana Ležaić , Nicola A. Spaldin

Titanates with the perovskite structure, including ferroelectrics (e.g., BaTiO$_3$) and ferromagnetic ones (e.g., YTiO$_3$), are important functional materials. Recent theoretical studies predicted multiferroic states in strained EuTiO$_3$…

Materials Science · Physics 2015-12-14 Ming An , Huimin Zhang , Yakui Weng , Yang Zhang , Shuai Dong

Multiferroic materials have attracted much interest due to the unusual coexistence of ferroelectric and (anti-)ferromagnetic ground states in a single compound. They offer an exciting platform for new physics and potentially novel devices.…

Strongly Correlated Electrons · Physics 2014-10-14 Je-Geun Park , Manh Duc Le , Jaehong Jeong , Sanghyun Lee

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

We studied structural, electronic and magnetic properties of a cubic perovskite BaFeO$_{3-\delta}$ ($0 \le \delta \le 0.5$) within the density functional theory using a generalized gradient approximation and a GGA+U method. According to our…

Materials Science · Physics 2016-01-20 I. V. Maznichenko , S. Ostanin , L. V. Bekenov , V. N. Antonov , I. Mertig , A. Ernst

Good quality and fine grain Bi6Fe2Ti3O18 magnetic ferroelectric films with single-phase layered perovskite structure have been successfully prepared via metal organic decomposition (MOD) method. Results of low-temperature magnetocapacitance…

Materials Science · Physics 2007-05-23 J. Lu , L. J. Qiao , X. Q. Ma , W. Y. Chu

We report here the realization of ferroelectricity, ferromagnetism and magnetocapacitance effect in SrFe12O19 ceramics at room temperature. The ceramics demonstrate a saturated polarization hysteresis loop, two I-V peaks and large anomaly…

Materials Science · Physics 2017-02-08 Guolong Tan , Yao Huang , Haohao Sheng

We report the structural and magnetoelectrical properties of La$_{0.7}$Ca$_{0.3}$MnO$_3$/BaTiO$_3$ perovskite superlattices grown on (001)-oriented SrTiO$_3$ by the pulsed laser deposition technique. Magnetic hysteresis loops together with…

Materials Science · Physics 2009-11-11 M. P. Singh , W. Prellier , Ch. Simon , B. Raveau

The perovskite oxide EuTiO3 (ETO) has attracted increased scientific interest due to its potential multiferroic properties and magnetic activity above and below its structural phase transition at TS=282K. Various experiments have indirectly…

The incompatibility of partial d occupation on the perovskite B-site with the standard charge transfer mechanism for ferroelectricity has been a central paradigm in multiferroics research. Nevertheless, it was recently shown by density…

Materials Science · Physics 2013-05-29 Claude Ederer , Tim Harris , Roman Kovacik

Multiferroic materials attract considerable interest because of the wide range of potential applications such as spintronic devices, data storage and sensors. As a strong candidate for the applications among the limited list of single-phase…

Materials Science · Physics 2016-09-21 J. S. Hwang , Y. J. Yoo , J. -H. Kang , K. H. Lee , B. W. Lee , S. Y. Park , Y. P. Lee

From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

Materials Science · Physics 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

We show that the magnetism of double perovskite AFe_{1/2}M_{1/2}O_3 systems may be described by the Heisenberg model on the simple cubic lattice, where only half of sites are occupied by localized magnetic moments. The nearest-neighbor…

Materials Science · Physics 2015-01-16 R. O. Kuzian , I. V. Kondakova , A. -M. Dare , V. V. Laguta

In this paper we examine the role of crystal chemistry factors in creating conditions for formation of magnetoelectric ordering in BiFeO3. It is generally accepted that the main reason of the ferroelectric distortion in BiFeO3 is concerned…

Materials Science · Physics 2011-06-03 L. M. Volkova , D. V. Marinin

The synthesis and structural study of the stoichiometric perovskite La0.5Ba0.5CoO3 have allowed three forms to be isolated. Besides the disordered La0.5Ba0.5CoO3 and the perfectly ordered layered LaBaCo2O6, a third form called…

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

We describe the design of a new magnetic ferroelectric with large spontaneous magnetization and polarization using first-principles density functional theory. The usual difficulties associated with the production of robustly-insulating…

Materials Science · Physics 2011-11-09 Pio Baettig , Nicola Spaldin