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Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several…

Quantum degenerate molecules represent a new paradigm for fundamental studies and practical applications. Association of already quantum degenerate atoms into molecules provides a crucial shortcut around the difficulty of cooling molecules…

Quantum Gases · Physics 2010-08-11 Matt Mackie , Pierre Phou

We propose an alternative method to laser cooling. Our approach utilizes the extreme brightness of a supersonic atomic beam, and the adiabatic atomic coilgun to slow atoms in the beam or to bring them to rest. We show how internal-state…

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

We produce an ultracold and dense sample of rovibronic ground state Cs_2 molecules close to the regime of quantum degeneracy, in a single hyperfine level, in the presence of an optical lattice. The molecules are individually trapped, in the…

Heteronuclear alkali-metal dimers represent the class of molecules of choice for creating samples of ultracold molecules exhibiting an intrinsic large permanent electric dipole moment. Among them, the KCs molecule, with a permanent dipole…

Atomic Physics · Physics 2015-04-08 D. Borsalino , R. Vexiau , M. Aymar , E. Luc-Koenig , O. Dulieu , N. Bouloufa-Maafa

This theoretical paper investigates the formation of ground state molecules from ultracold cesium atoms in a two-color scheme. Following previous work on photoassociation with chirped picosecond pulses [Luc-Koenig et al., Phys. Rev. A {\bf…

Atomic Physics · Physics 2007-05-23 Christiane P. Koch , Eliane Luc-Koenig , Françoise Masnou-Seeuws

Laser cooling of translational motion of small molecules is performed by addressing transitions that ensure spontaneous emission cannot cause net rotational excitation. This will not be possible once the rotational splitting becomes…

Quantum Physics · Physics 2022-03-08 W. C. Campbell , B. L. Augenbraun

We investigate the dynamics of molecular photoexcitation by unchirped femtosecond laser pulses using RbCs as a model system. This study is motivated by a goal of optimizing a two-color scheme of transferring vibrationally-excited ultracold…

Atomic Physics · Physics 2015-06-04 B. E. Londono , A. Derevianko , J. E. Mahecha , A. Crubellier , E. Luc-Koenig

Ultracold ground-state molecules can be formed from ultracold atoms via photoassociation followed by a spontaneous emission process. Typically, the molecular products are distributed over a range of final states. Here, we propose to use an…

Quantum Physics · Physics 2018-12-20 Tobias Kampschulte , Johannes Hecker Denschlag

The semiclassical theory of laser cooling is applied for the analysis of cooling of unbound atoms with the values of the ground and exited state angular moments 1/2 in a one-dimensional nondissipative optical lattice. We show that in the…

Optics · Physics 2011-10-05 N. A. Matveeva , A. V. Taichenachev , A. M. Tumaikin , V. I. Yudin

We propose a method for achieving highly efficient transfer between the vibrational states in a diatomic molecule. The process is mediated by strong laser pulses and can be understood in terms of light-induced potentials. In addition to…

Quantum Physics · Physics 2009-11-06 M. Rodriguez , K. -A. Suominen , B. M. Garraway

A method of sideband Raman cooling to the vibrational ground state of the $m=0$ Zeeman sublevel in a far-detuned two-dimensional optical lattice is proposed. In our scheme, the Raman coupling between vibrational manifolds of the adjacent…

Atomic Physics · Physics 2007-05-23 A. V. Taichenachev , A. M. Tumaikin , V. I. Yudin , L. Hollberg

Optical pumping is a technique for engineering atomic-sublevel population of desired atoms. We investigate the population evolution of Cesium atoms by employing Liouville equation. For this purpose, we apply a circularly polarized light at…

Atomic Physics · Physics 2024-03-22 Hossein Davoodi Yeganeh , Zahra Shaterzadeh-Yazdi

Ultracold gases in optical lattices are of great interest, because these systems bear a great potential for applications in quantum simulations and quantum information processing, in particular when using particles with a long-range…

Statistical Mechanics · Physics 2007-05-23 T. Volz , N. Syassen , D. M. Bauer , E. Hansis , S. Dürr , G. Rempe

Selectively exciting target molecules to high vibrational states is inefficient in the liquid phase, which restricts the use of IR pumping to catalyze ground-state chemical reactions. Here, we demonstrate that this inefficiency can…

Chemical Physics · Physics 2022-12-27 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

We propose to sympathetically slow and cool polar molecules in a cold, low-density beam using laser-cooled Rydberg atoms. The elastic collision cross sections between molecules and Rydberg atoms are large enough to efficiently thermalize…

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

Atomic Physics · Physics 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

A novel laser cooling mechanism based on many body effects is presented. The method can be applicable for cooling a large class of atoms and molecules in higher density than commonly excepted by existing methods. The cooling mechanism…

Atomic Physics · Physics 2021-03-11 Roie Dann , Ronnie Kosloff