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Raman-based technologies have enabled many ground-breaking scientific discoveries related to surface science, single molecule chemistry and biology. For example, researchers have identified surface bound molecules by their Raman vibrational…

Optics · Physics 2020-03-12 Xiaoqin Shen , Hyungwoo Choi , Dongyu Chen , Wei Zhao , Andrea M. Armani

Dynamic surface-enhanced Raman spectroscopy (SERS) is nowadays one of the most interesting applications of SERS, in particular for single molecule studies. In fact, it enables the study of real-time processes at the molecular level. This…

By using scattering in near field techniques, a microscope can be easily turned into a device measuring static and dynamic light scattering, very useful for the characterization of nanoparticle dispersions. Up to now, microscopy based…

Optics · Physics 2015-05-13 D. Brogioli , D. Salerno , V. Cassina , F. Mantegazza

Tip enhanced IR spectra and imaging have been widely used in cutting-edge studies for the in-depth understanding of the composition, structure and function of interfaces at the nanoscale. However, molecular monolayer sensitivity has only…

By combining first principles theoretical calculations and experimental optical and structural characterization such as spectroscopic ellipsometry, X-ray spectroscopy, and electron microscopy, we study the dielectric permittivity and…

Mesoscale and Nanoscale Physics · Physics 2017-12-19 Deesha Shah , Alessandra Catellani , Harsha Reddy , Nathaniel Kinsey , Vladimir Shalaev , Alexandra Boltasseva , Arrigo Calzolari

We discuss how variations in the scanning tunneling microscope (STM) tip, whether unintentional or intentional, can lead to changes in topographic images and dI/dV spectra. We consider the possibility of utilizing functionalized tips in…

Superconductivity · Physics 2015-05-28 Ilpo Suominen , Jouko Nieminen , R. S. Markiewicz , A. Bansil

Surface enhanced Raman scattering mediated by surface plasmons polaritons with wave vector much larger than those of light is considered. The excitation of these polaritons and their efficient Raman scattering due to low group velocity and…

Optics · Physics 2015-06-04 Tomas Lopez-Rios

Non-Hermitian systems hosting exceptional points (EPs) exhibit signal enhancement and unconventional mode dynamics. Going beyond isolated EPs, here we report on the existence of exceptional rings (ERs) in planar optical resonators with…

We investigate the interplay of shape changes and localized surface plasmons in small metal particles with the potential of a large enhancement of the Raman signal from the particles own vibrations. The framework is a geometrical one where…

Optics · Physics 2016-01-26 S. P. Apell , G. Mukhopadhyay , Tomasz Antosiewicz , J Aizpurua

We analyze how a probing particle modifies the infrared electromagnetic near field of a sample. The particle, described by electric and magnetic polarizabilities, represents the tip of an apertureless scanning optical near-field microscope…

The characteristic tip_substrate capacitance is crucial for understanding the localized electrical properties in atomic force microscopy (AFM). Since it is highly dependent on tip geometrical features, estimation of the tip_substrate…

Mesoscale and Nanoscale Physics · Physics 2016-01-25 Reynier I. Revilla

Surface enhanced Raman spectroscopy (SERS) is a precise and non-invasive analytical technique that is widely used in chemical analysis, environmental protection, food processing, pharmaceutics, and diagnostic biology. However, it is still a…

Stokes Raman scattering is known to be a particularly robust nonlinearity, occurring in virtually every material, with spectra defined by the material and strengths dependent on the material as well as light intensities. This ubiquity has…

Optics · Physics 2021-08-10 Xiao Liu , Zelin Ma , Aku Antikainen , Siddharth Ramachandran

This paper reports on the excitation of surface plasmons on gold-coated nanofibre tips by side-illumination with a laser beam and the coupling of the surface plasmons to the optical fiber. The measurements show a strong dependence of the…

Optics · Physics 2015-06-16 D. Auwärter , C. Zimmermann , S. Slama

Surface plasmon resonance (SPR) has been intensively studied and widely employed for light trapping and absorption enhancement. In the mid-infrared and terahertz (THz) regime, graphene supports the tunable SPR via manipulating its Fermi…

Optics · Physics 2017-11-15 Shuyuan Xiao , Tao Wang , Yuebo Liu , Chen Xu , Xu Han , Xicheng Yan

Raman spectroscopy is a valuable characterization tool for two-dimensional materials. Starting from model Hamiltonians for Chern insulators and magnetized monolayers of transition metal dichalcogenides, we theoretically predict two…

Mesoscale and Nanoscale Physics · Physics 2025-01-29 Selçuk Parlak , Ion Garate

Scanning tunneling microscopes (STM) are used extensively for studying and manipulating matter at the atomic scale. In spite of the critical role of the STM tip, the control of the atomic-scale shape of STM tips remains a poorly solved…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 Sumit Tewari , Koen M. Bastiaans , Milan P. Allan , Jan M. van Ruitenbeek

Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement…

Raman spectroscopy provides spectral information related to the specific molecular structures of substances and has been well established as a powerful tool for studying biological tissues and diagnosing diseases. This article reviews…

A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , M. Meyer , P. G. Etchegoin
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