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The cubic perovskite-related ceramic CaCu3Ti4O12 has a very high static dielectric constant ~10000 at room temperature (RT), which drops to about 100 below about 100 K. Substituting Cd for Ca reduces the RT value of the dielectric constant…

Strongly Correlated Electrons · Physics 2007-05-23 C. C. Homes , T. Vogt , S. M. Shapiro , W. Si , S. Wakimoto , M. A. Subramanian

The dielectric constant of CaCu3Ti4O12 is measured with a different electrode geometry than previous measurements. Similar colossal values are obtained showing that they are "intrinsic" to the material. We show that in braced structures…

Condensed Matter · Physics 2007-05-23 A. P. Ramirez , G. Lawes , V. Butko , M. A. Subramanian , C. M. Varma

First-principles calculations were used to compute the dielectric permittivities of hypothetical [La,Sc]2O3 solid solutions in the cubic (bixbyite) and hexagonal La2O3 phases. Dielectric enhancement is predicted at small Sc concentrations…

Materials Science · Physics 2010-04-09 Hiroyoshi Momida , Eric Cockayne , Naoto Umezawa , Takahisa Ohno

$\alpha$-RuCl$_3$ is a Mott insulator with a honeycomb lattice with strong spin-orbit coupling. We report dielectric measurements on $\alpha$-RuCl$_3$ single crystals under field. At zero field, the dielectric constant, $\epsilon$, drops…

Strongly Correlated Electrons · Physics 2018-02-20 Jia-Cheng Zheng , Yi Cui , Tian-Run Li , Ke-Jing Ran , Jinsheng Wen , Weiqiang Yu

Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and…

Chemical Physics · Physics 2007-05-23 Francesca Terenziani , Anna Painelli , Zoltan G. Soos

Modern semiconductor materials are increasingly used in multidisciplinary systems demonstrating cross-interactions between mechanical strains and electronic potentials, which gives rise to ubiquitous applications in high sensitivity,…

Materials Science · Physics 2021-06-04 Lijie Li

We study the effects of insulating oxides in their crystalline forms on the energy band structure of monolayer and bilayer graphene using a \textit{first principles} density functional theory based electronic structure method and a local…

Materials Science · Physics 2011-12-09 Priyamvada Jadaun , Sanjay K. Banerjee , Leonard F. Register , Bhagawan Sahu

The effect of pressure on the low-frequency dielectric constant, $\epsilon_0$, of single crystals of KNbO_3 is investigated by means of capacitance measurements. The dielectric constant increases with pressure up to 22.5 kbar, where it…

Materials Science · Physics 2016-08-15 D. Errandonea , E. Moya

We discuss a non-perturbative, technically straightforward, easy-to-use, and computationally affordable method, based on polarization theory, for the calculation of the electronic dielectric constant of insulating solids at the first…

Materials Science · Physics 2009-10-31 Fabio Bernardini , Vincenzo Fiorentini

Ba{[Gax,Tax]Ti(1-2x)}O3 ceramics with x equal to 0, 0.0025, 0.005, 0.01, 0.025 and 0.05 have been prepared by conventional solid-state reaction. Structural and dielectric characterization have been performed to investigate the effect of…

The control of the dielectric and conductive properties of device-level systems is important for increasing the efficiency of energy- and information-related technologies. In some cases, such as neuromorphic computing, it is desirable to…

Mesoscale and Nanoscale Physics · Physics 2020-07-28 Dimitrios Fraggedakis , Mohammad Mirzadeh , Tingtao Zhou , Martin Z. Bazant

We define the dielectric constant (susceptibility) that should enter the Maxwell boundary value problem when applied to microscopic dielectric interfaces. The dielectric constant (susceptibility) of the interface is defined by exact…

Soft Condensed Matter · Physics 2016-08-03 Mohammadhasan Dinpajooh , Dmitry V. Matyushov

High-k oxides such as SrTiO3 promise large capacitance, but their dielectric response is often limited by leakage currents due to reduced bandgaps. We show that introducing a thin barrier layer beneath SrTiO3 is a simple and effective way…

High-k dielectric materials are important as gate oxides in microelectronics and as potential dielectrics for capacitors. In order to enable computational discovery of novel high-k dielectric materials, we propose a fitness model (energy…

The search for new materials with extremely high ("colossal") dielectric constants, required for future electronics, is one of the most active fields of modern materials science. However, the applicability of the colossal-epsilon'…

Materials Science · Physics 2009-03-24 S. Krohns , P. Lunkenheimer , Ch. Kant , A. V. Pronin , H. B. Brom , A. A. Nugroho , M. Diantoro , A. Loidl

Enhancement of the dielectric response of insulators by disorder is theoretically proposed, where the quantum interference of electronic waves through the nanoscale/mesoscopic system and its change due to external perturbations control the…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Shigeki Onoda , Chyh-Hong Chern , Shuichi Murakami , Yasushi Ogimoto , Naoto Nagaosa

We have measured dielectric properties of Ca$_{1+x}$Cu$_{3-x}$Ti$_4$O$_{12}$ ($x$ = 0, 0.1, 0.5, 1, 1.5, 2, 2.9 and 3), and have found that Ca$_2$Cu$_2$Ti$_4$O$_{12}$ (a composite of CaCu$_3$Ti$_4$O$_{12}$ and CaTiO$_3$) exhibits a high…

Materials Science · Physics 2009-11-11 W. Kobayashi , I. Terasaki

Thermoelectric properties of the layered cobalt oxide system LixCoO2 were investigated in a wide range of Li composition, 0.98 >= x >= 0.35. Single-phase bulk samples of LixCoO2 were successfully obtained through electrochemical…

Strongly Correlated Electrons · Physics 2011-05-25 T. Motohashi , Y. Sugimoto , Y. Masubuchi , T. Sasagawa , W. Koshibae , T. Tohyama , H. Yamauchi , S. Kikkawa

Silicon oxide (SiOx) has been widely used in many electronic systems as a supportive and insulating medium. Here we demonstrate various electrical phenomena such as negative differential resistance, resistive switching and current…

Materials Science · Physics 2011-02-17 Jun Yao , Lin Zhong , Douglas Natelson , James M. Tour

Recently an improved limits on the electron electric dipole moment, \eEDM, and dimensionless constant, $k_{T,P}$, characterizing the strength of the T,P-odd pseudoscalar$-$scalar electron$-$nucleus neutral current interaction in the…

Atomic Physics · Physics 2015-01-13 L. V. Skripnikov , A. V. Titov