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Recent experiments and computer simulations show that supercooled liquids around the glass transition temperature are "dynamically heterogeneous" [1]. Such heterogeneity is expected from the random first order transition theory of the glass…

Disordered Systems and Neural Networks · Physics 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

We present molecular dynamics results for a two component, two-dimensional Lennard-Jones supercooled liquid near the glass transition. We find that the supercooled liquid is spatially heterogeneous and that there are long-lived clusters…

Disordered Systems and Neural Networks · Physics 2009-10-31 Gregory Johnson , Andrew I. Melcuk , Harvey Gould , W. Klein , Raymond D. Mountain

We explore the nature of glass-formation in variable spatial dimensionality ($d$) based on the generalized entropy theory, a synthesis of the Adam-Gibbs model with direct computation of the configurational entropy of polymer fluids using an…

Soft Condensed Matter · Physics 2016-11-09 Wen-Sheng Xu , Jack F. Douglas , Karl F. Freed

The following properties are in the present literature associated with the behavior of super-cooled glass-forming liquids: faster than exponential growth of the relaxation time, dynamical heterogeneities, growing point-to-set correlation…

Statistical Mechanics · Physics 2011-01-25 Florent Krzakala , Lenka Zdeborová

The connection between domain relaxations at individual scales and the collective heterogeneous response in non-equilibrium systems is a topic of profound interest in recent times. In a model sys- tem of constantly driven oppositely charged…

Soft Condensed Matter · Physics 2016-12-16 Suman Dutta

While the transformation of flowing liquids into rigid glasses is omnipresent, a complete understanding of vitrification remains elusive. Of the numerous approaches aimed at solving the glass transition problem, the Random First-Order…

Soft Condensed Matter · Physics 2015-05-20 K. Hima Nagamanasa , Shreyas Gokhale , A. K. Sood , Rajesh Ganapathy

We report results of molecular dynamics simulations of a binary Lennard-Jones system at zero pressure in the undercooled liquid and glassy states. We first follow the evolution of diffusivity and dynamic heterogeneity with temperature and…

Disordered Systems and Neural Networks · Physics 2007-05-23 H. R. Schober

The dynamical heterogeneities (DH) in non-ergodic states of an attractive colloidal glass are studied, as a function of the waiting time. Whereas the fluid states close to vitrify showed strong DH, the distribution of squared displacements…

Soft Condensed Matter · Physics 2009-11-11 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

The effects of randomly pinning particles in a model glass-forming fluid are studied, with a focus on the dynamically heterogeneous relaxation in the presence of pinning. We show how four-point dynamical correlations can be analysed in real…

Statistical Mechanics · Physics 2013-10-30 Robert L. Jack , Christopher J. Fullerton

We demonstrate that an extended picture of kinetic constraints in glass-forming liquids is sufficient to explain dynamic anomalies observed in dense suspensions of strongly attracting colloidal particles. We augment a simple model of…

Statistical Mechanics · Physics 2009-11-10 Phillip L. Geissler , David R. Reichman

We identify the pattern of microscopic dynamical relaxation for a two dimensional glass forming liquid. On short timescales, bursts of irreversible particle motion, called cage jumps, aggregate into clusters. On larger time scales, clusters…

Soft Condensed Matter · Physics 2010-10-04 R. Candelier , A. Widmer-Cooper , J. K. Kummerfeld , O. Dauchot , G. Biroli , P. Harrowell , D. R. Reichman

We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…

Statistical Mechanics · Physics 2011-10-10 Ludovic Berthier , Gilles Tarjus

A two-dimensional bidisperse granular fluid is shown to exhibit pronounced long-ranged dynamical heterogeneities as dynamical arrest is approached. Here we focus on the most direct approach to study these heterogeneities: we identify…

Disordered Systems and Neural Networks · Physics 2017-10-27 Karina E. Avila , Horacio E. Castillo , Katharina Vollmayr-Lee , Annette Zippelius

The glass transition, extensively studied in dense fluids, polymers, or colloids, corresponds to a dramatic evolution of equilibrium transport coefficients upon a modest change of control parameter, like temperature or pressure. A similar…

Statistical Mechanics · Physics 2013-05-06 Ludovic Berthier , Jorge Kurchan

Lithium disilicate glasses and glass-ceramics are good potential candidates for biomedical applications and solid-state batteries, and serve as models of nucleation and crystal growth. Moreover, these glasses exhibit a phase separation that…

Liquids near the glass transition exhibit dynamical heterogeneity, i.e. local relaxation rates fluctuate strongly over space and time. Here we introduce a simple continuum model that allows for quantitative predictions for the correlators…

Soft Condensed Matter · Physics 2024-03-20 Rajib K. Pandit , Horacio E. Castillo

Understanding and controlling physical aging, i.e. the spontaneous temporal evolution of out-of-equilibrium systems, represents one of the greatest tasks in material science. Recent studies have revealed the existence of a complex atomic…

Materials Science · Physics 2016-02-17 V. M. Giordano , B. Ruta

We study dynamical heterogeneity and growing dynamical lengthscales in two kinetically constrained models, namely, the one- and two-vacancy assisted triangular lattice gases. One of the models is a strong glassformer and the other is a…

Statistical Mechanics · Physics 2009-11-10 Albert C. Pan , Juan P. Garrahan , David Chandler

We study experimentally the origin of heterogeneous dynamics in strongly driven glass-forming systems. Thereto, we apply a well-defined force with a laser line trap on individual colloidal polystyrene probe particles seeded in an emulsion…

Soft Condensed Matter · Physics 2019-03-27 Nesrin Şenbil , Markus Gruber , Chi Zhang , Matthias Fuchs , Frank Scheffold

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks