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Glasses are ubiquitous in daily life and technology. However the microscopic mechanisms generating this state of matter remain subject to debate: Glasses are considered either as merely hyper-viscous liquids or as resulting from a genuine…

Disordered Systems and Neural Networks · Physics 2016-06-14 S. Albert , Th. Bauer , M. Michl , G. Biroli , J. -P. Bouchaud , A. Loidl , P. Lunkenheimer , R. Tourbot , C. Wiertel-Gasquet , F. Ladieu

The presence of dynamical heterogeneities, i.e. nanometer-scale regions containing molecules rearranging cooperatively at very different rates compared to the bulk, is increasingly being recognized as crucial in our understanding of the…

Disordered Systems and Neural Networks · Physics 2015-06-25 Horacio E. Castillo , Azita Parsaeian

We perform molecular dynamics simulations of a model glass-forming liquid to measure the size of kinetic heterogeneities, using a dynamic susceptibility $\chi_{\rm ss}(a, t)$ that quantifies the number of particles whose dynamics are…

Soft Condensed Matter · Physics 2014-04-04 T. K. Haxton , A. J. Liu

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

Soft Condensed Matter · Physics 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

Using molecular dynamics simulations, we have determined that the nature of dynamical heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly attractive systems differ little from dense hard-sphere and…

Soft Condensed Matter · Physics 2007-05-23 David R. Reichman , Eran Rabani , Phillip L. Geissler

Existence and growth of amorphous order in supercooled liquids approaching glass transition is a subject of intense research. Even after decades of work, there is still no clear consensus on the molecular mechanisms that lead to a rapid…

Statistical Mechanics · Physics 2023-03-14 Rajsekhar Das , Saurish Chakrabarty , Smarajit Karmakar

At the microscopic level, equilibrium liquid's translational symmetry is spontaneously broken at the so-called dynamic glass transition predicted by the mean-field replica approach. We show that this fact implies the emergence of Goldstone…

Statistical Mechanics · Physics 2015-05-28 Grzegorz Szamel , Elijah Flenner

As the glass (in molecular fluids\cite{Donth}) or the jamming (in colloids and grains\cite{LiuNature1998}) transitions are approached, the dynamics slow down dramatically with no marked structural changes. Dynamical heterogeneity (DH) plays…

Soft Condensed Matter · Physics 2008-07-03 Pierre Ballesta , Agnes Duri , Luca Cipelletti

We show that the slowing of the dynamics in simulations of several model glass-forming liquids is equivalent to the hard-sphere glass transition in the low-pressure limit. In this limit, we find universal behavior of the relaxation time by…

Soft Condensed Matter · Physics 2009-12-17 Ning Xu , Thomas K. Haxton , Andrea J. Liu , Sidney R. Nagel

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

Soft Condensed Matter · Physics 2015-06-11 C. Patrick Royall , Stephen R. Williams

The solidity of glassy materials is believed to be due to the cage formed around each particle by its neighbors, but in reality the details of cage-formation remain elusive [1-4]. This cage starts to be formed at the onset…

Soft Condensed Matter · Physics 2020-12-02 Bo Li , Kai Lou , Walter Kob , Steve Granick

We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

We investigate the translational and rotational relaxation dynamics of a crowded two-dimensional system of monodisperse Penrose kites, in which crystallization, quasi-crystallization, and nematic ordering are suppressed, from low to high…

Soft Condensed Matter · Physics 2020-01-15 Yan-Wei Li , Zi-Qi Li , Zhang-Lin Hou , Thomas G. Mason , Kun Zhao , Zhao-Yan Sun , Massimo Pica Ciamarra

A link between structural ordering and slow dynamics has recently attracted much attention from the context of the origin of glassy slow dynamics. Candidates for such structural order are icosahedral, exotic amorphous, and crystal-like.…

Soft Condensed Matter · Physics 2013-01-31 Mathieu Leocmach , Hajime Tanaka

We present an event-driven molecular dynamics study of glass formation in two-dimensional binary mixtures composed of hard disks and hard ellipses, where both types of particles have the same area. We demonstrate that characteristic…

Soft Condensed Matter · Physics 2015-05-27 Wen-Sheng Xu , Xiaozheng Duan , Zhao-Yan Sun , Li-Jia An

Hierarchical dynamics in glass-forming systems span multiple timescales, from fast vibrations to slow structural rearrangements, appearing in both supercooled fluids and glassy states. Understanding how these diverse processes interact…

Soft Condensed Matter · Physics 2025-05-28 Wensi Sun , Yanshuang Chen , Wencheng Ji , Yi Zhou , Hua Tong , Ke Chen , Xiaosong Chen , Hajime Tanaka , Peng Tan

The dynamical arrest of gels is the consequence of a well defined structural phase transition, leading to the formation of a spanning cluster of bonded particles. The dynamical glass transition, instead, is not accompanied by any clear…

Soft Condensed Matter · Physics 2016-07-21 Raffaele Pastore , Antonio de Candia , Anallisa Fierro , Massimo Pica Ciamarra , Antonio Coniglio

This perspective article reviews arguments that glass-forming liquids are different from those of standard liquid-state theory, which typically have a viscosity in the mPa$\cdot$s range and relaxation times of order picoseconds. These…

Soft Condensed Matter · Physics 2024-02-13 Jeppe C. Dyre

The dynamics of dislocations is reported to exhibit glassy properties. We study numerically various versions of 2d edge dislocation systems in the absence of externally applied stress. Two types of glassy behavior are identified: (i)…

Disordered Systems and Neural Networks · Physics 2009-11-13 B. Bako , I. Groma , G. Gyorgyi , G. T. Zimanyi
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