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Charge regulation is an important aspect of electrostatics in biological and colloidal systems, where the charges are generally not fixed, but depend on the environmental variables. Here, we analyze the charge regulation mechanism in…

Soft Condensed Matter · Physics 2018-08-01 Anže Lošdorfer Božič , Rudolf Podgornik

Colloidal dispersions composed of polymethylmetacrylate particles dispersed in a mixture of cyclohexylbromide and decalin find widespread use as model systems in optical microscopy experiments. While the system allows simultaneous density…

Soft Condensed Matter · Physics 2024-01-11 Marcel Rudolf , Andreas Zumbusch

We analyse charge inversion in colloidal systems at zero temperature using stability concepts, and connect this to the classical Thomson problem of arranging electrons on sphere. We show that for a finite microion charge, the globally…

Chemical Physics · Physics 2009-11-07 Michael Patra , Marco Patriarca , Mikko Karttunen

Resonance Raman experiments on doped and photoexcited single crystals of mixed-halide $MX$ complexes ($M$=Pt; $X$=Cl,Br) clearly indicate charge separation: electron polarons preferentially locate on PtBr segments while hole polarons are…

Condensed Matter · Physics 2009-10-22 L. A. Worl , S. C. Huckett , B. I. Swanson , A. Saxena , A. R. Bishop , J. Tinka Gammel

We investigate theoretically the phase diagram of an insoluble charged surfactant monolayer in contact with a semi-dilute polyelectrolyte solution (of opposite charge). The polyelectrolytes are assumed to have long-range and attractive…

Soft Condensed Matter · Physics 2012-07-19 Adi Shafir , David Andelman

Atomically thin transition metal dichalcogenides can exhibit markedly different electronic properties compared to their bulk counterparts. In the case of NbSe$_2$, the question of whether its charge density wave (CDW) phase is enhanced in…

In single particle imaging experiments, beams of individual nanoparticles are exposed to intense pulses of x-rays from free-electron lasers to record diffraction patterns of single, isolated molecules. The reconstruction for structure…

This paper presents the results of a rheological study of thermotropic nematic colloids aggregated into cellular structures. Small sterically stabilised PMMA particles dispersed in a liquid crystal matrix densely pack on cell interfaces,…

Soft Condensed Matter · Physics 2009-10-31 V. J. Anderson , E. M. Terentjev

In a recent Letter, Gurovitch and Sens studied the adsorption of a weakly charged polyelectrolyte chain onto an oppositely charged colloidal particle. By using a variational technique they found that the colloidal particle can adsorb a…

Soft Condensed Matter · Physics 2009-10-31 Ramin Golestanian

We study metastable clusters in a colloidal system with competing interactions. A short-ranged polymer-induced attraction drives clustering, while a weak, long-ranged electrostatic repulsion prevents extensive aggregation. We compare…

In recent years, there has been a renewed interest in complex coacervation, driven by concerted efforts to offer novel experimental and theoretical insights into electrostatic charge-induced association. While previous studies have…

Soft Condensed Matter · Physics 2024-10-30 Letícia Vitorazi , Jean-François Berret

We investigate the polarization dependence of optical nonlinearity enhancement for a uniaxial anisotropic composite of metal nanocrystals in a dielectric host. Three cases are distinguished depending on whether the polarization is parallel,…

Soft Condensed Matter · Physics 2007-05-23 K. P. Yuen , M. F. Law , K. W. Yu , Ping Sheng

By making use of circularly polarized light and electrostatic gating, monolayer molybdenum disulfide (ML-MoS$_2$) can form a platform supporting multiple types of charge carriers. They can be discriminated by their spin, valley index or…

Mesoscale and Nanoscale Physics · Physics 2017-08-17 Y. M. Xiao , W. Xu , F. M. Peeters , B. Van Duppen

We study the percolation properties for a system of functionalized colloids on patterned substrates via Monte Carlo simulations. The colloidal particles are modeled as hard disks with three equally-distributed attractive patches on their…

Soft Condensed Matter · Physics 2018-03-02 Lucas L. Treffenstädt , Nuno A. M. Araújo , Daniel de las Heras

Phase separation in salt-free symmetric mixtures of oppositely charged rodlike polyelectrolytes is studied using quasi-analytical calculations. Stability analyses for the isotropic-isotropic and the isotropic-nematic phase transitions in…

Soft Condensed Matter · Physics 2010-07-20 Rajeev Kumar , Debra Audus , Glenn H. Fredrickson

The electronic polarization energies, P = (P+) + (P-), of a PTCDA (perylenetetracarboxylic acid dianhydride) cation and anion in a crystalline thin film on a metallic substrate are computed and compared with measurements of the PTCDA…

Condensed Matter · Physics 2009-11-07 E. V. Tsiper , Z. G. Soos , W. Gao , A. Kahn

The effects of image charges (i.e., induced surface charges of polarization) in spherical geometry and their implication for charged colloidal systems are investigated. We study analytically and exactly a single microion interacting with a…

Soft Condensed Matter · Physics 2007-05-23 Rene Messina

In systems of highly charged linear polyelectrolytes and oppositely charged colloidal particles, long-lived clusters of polyelectrolyte-decorated particles form in an interval of concentrations around the isoelectric point, where reentrant…

Soft Condensed Matter · Physics 2008-07-24 S. Sennato , D. Truzzolillo , F. Bordi , C. Cametti

A mesoscopic colloid model is developed in which a spherical colloid is represented by many interacting sites on its surface. The hydrodynamic interactions with thermal fluctuations are taken accounts in full using Dissipative Particle…

Soft Condensed Matter · Physics 2014-01-16 Jiajia Zhou , Friederike Schmid

The surface conductivity is measured by a four-probe technique for pentacene and rubrene single-crystals laminated on polarized and nearly unpolarized molecular monolayers with application of perpendicular electric fields. The polarization…

Materials Science · Physics 2009-11-10 J. Takeya , T. Nishikawa , T. Takenobu , S. Kobayashi , C. Goldmann , C. Krellner , T. Shimoda , T. Mitani , Y Iwasa , B. Batlogg