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Microcanonical equations for several thermodynamic properties of a system, suitable for molecular dynamics simulations, are derived from the nonextensive Tsallis entropy functional. Two possible definitions of temperature, the usual one and…

Statistical Mechanics · Physics 2011-03-21 J. Carrete , L. M. Varela , L. J. Gallego

The Gibbs distribution universally characterizes states of thermal equilibrium. In order to extend the Gibbs distribution to non-equilibrium steady states, one must relate the self-information $\mathcal{I}(x) = -\log(P_\text{ss}(x))$ of…

Statistical Mechanics · Physics 2023-04-04 Nahuel Freitas , Massimiliano Esposito

We develop an exact quantum thermodynamic description for a noninteracting nanoscale steady state that couples strongly with multiple reservoirs. It is demonstrated that there exists a steady-state extension of the thermodynamic function…

Mesoscale and Nanoscale Physics · Physics 2018-04-05 Nobuhiko Taniguchi

This paper shows how mesoscopic nonequilibrium thermodynamics can be applied to condensation and evaporation. By extending the normal set of thermodynamic variables with two internal variables, we are able to give a new theoretical…

Statistical Mechanics · Physics 2009-11-10 D. Bedeaux , S. Kjelstrup , J. M. Rubi

For time-dependent states generated by an external operation, a generalized free energy may be introduced by the relative entropy with respect to an equilibrium state realized after sufficient relaxation from the time-dependent states.…

Statistical Mechanics · Physics 2013-02-13 Naoko Nakagawa , Shin-ichi Sasa

The quasi-stationary nonequilibrium distribution function of an independent electron gas interacting with a medium, which is at local thermal equilibrium, can be obtained by entropy production rate minimization, subject to constraints of…

Statistical Mechanics · Physics 2010-05-18 Thomas Christen

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We show how to construct non-equilibrium thermodynamics for systems too small to be considered thermodynamically in a traditional sense. Through the use of a non-equilibrium ensemble of many replicas of the system which can be viewed as a…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi , D. Bedeaux , S. Kjelstrup

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

We give a modified derivation of the Einstein equation of state by considering the Clausius relation $T\delta S-\delta N =\delta Q$ on a null hypersurface with a non-vanishing expansion ($\theta \neq 0$), i.e. not in the equilibrium. The…

General Relativity and Quantum Cosmology · Physics 2012-10-11 Kengo Shimada , Susumu Okazawa , Satoshi Iso

A system can be driven out of equilibrium by both time-dependent and nonconservative forces, which gives rise to a decomposition of the dissipation into two non-negative components, called the excess and housekeeping entropy productions. We…

Statistical Mechanics · Physics 2023-05-31 Takuya Kamijima , Sosuke Ito , Andreas Dechant , Takahiro Sagawa

We use the work done on and the heat removed from a system to maintain it in a nonequilibrium steady state for a thermodynamic-like description of such a system as well as of its fluctuations. Based on a generalized Onsager-Machlup theory…

Statistical Mechanics · Physics 2008-02-10 Tooru Taniguchi , E. G. D. Cohen

The accurate determination of transport coefficients in numerical simulations is becoming increasingly important in a wide range of applications. Here we consider the linear response in systems driven away from thermal equilibrium into a…

Statistical Mechanics · Physics 2016-08-24 Thomas Speck

We study the nonequilibrium statistical mechanics of a finite classical system subjected to nongradient forces $\xi$ and maintained at fixed kinetic energy (Hoover-Evans isokinetic thermostat). We assume that the microscopic dynamics is…

Statistical Mechanics · Physics 2007-05-23 David Ruelle

Following the proposal of steady state thermodynamics (SST) by Oono and Paniconi, we develop a phenomenological theory for steady nonequilibrium states in systems with heat conduction. We find that there is essentially a unique consistent…

Statistical Mechanics · Physics 2007-05-23 Shin-ichi Sasa , Hal Tasaki

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…

Statistical Mechanics · Physics 2022-11-30 Robert Hołyst , Karol Makuch , Anna Maciołek , Paweł J. Żuk

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

The linear response to temperature changes is derived for systems with overdamped stochastic dynamics. Holding both in transient and steady state conditions, the results allow to compute nonequilibrium thermal susceptibilities from…

Statistical Mechanics · Physics 2016-04-11 Gianmaria Falasco , Marco Baiesi