English

Nonequilibrium thermodynamics as a gauge theory

Statistical Mechanics 2015-05-30 v3

Abstract

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential. A widely accepted expression for the total entropy production of a system arises as the simplest gauge-invariant completion of the time derivative of Gibbs's entropy. We show that transition rates can be given a simple physical characterization in terms of locally-detailed-balanced heat reservoirs. It follows that Clausius's measure of irreversibility along a cyclic transformation is a geometric phase. In this picture, the gauge symmetry arises as the arbitrariness in the choice of a prior probability. Thermostatics depends on the information that is disposable to an observer; thermodynamics does not.

Keywords

Cite

@article{arxiv.1110.0608,
  title  = {Nonequilibrium thermodynamics as a gauge theory},
  author = {Matteo Polettini},
  journal= {arXiv preprint arXiv:1110.0608},
  year   = {2015}
}

Comments

6 pages. Non-fatal errors in eq.(6), eq.(26) and eq.(31) have been amended

R2 v1 2026-06-21T19:14:42.445Z