English

Work relations for time-dependent states

Statistical Mechanics 2013-02-13 v2

Abstract

For time-dependent states generated by an external operation, a generalized free energy may be introduced by the relative entropy with respect to an equilibrium state realized after sufficient relaxation from the time-dependent states. Recently, by studying over-damped systems, Sivak and Crooks presented a formula that relates the generalized free energy with measurable thermodynamic works. We re-derive this relation with emphasizing a connection to an extended Clausius relation proposed in the framework of steady state thermodynamics. As a natural consequence, we generalize this relation to be valid for systems with momentum degrees of freedom, where the Shannon entropy in the generalized free energy is replaced by a symmetric one.

Keywords

Cite

@article{arxiv.1211.6203,
  title  = {Work relations for time-dependent states},
  author = {Naoko Nakagawa and Shin-ichi Sasa},
  journal= {arXiv preprint arXiv:1211.6203},
  year   = {2013}
}

Comments

5 pages, 2 figures

R2 v1 2026-06-21T22:44:36.283Z