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Measurements of polarization and temperature dependent soft x-ray absorption have been performed on Na_xCoO_2 single crystals with x=0.4 and x=0.6. They show a deviation of the local trigonal symmetry of the CoO_6 octahedra, which is…

Strongly Correlated Electrons · Physics 2009-11-11 T. Kroll , M. Knupfer , J. Geck , C. Hess , T. Schwieger , G. Krabbes , C. Sekar , D. R. Batchelor , H. Berger , B. Buechner

We have performed a temperature-dependent photoemission study of a NaxCoO2 (x~0.8) epitaxial thin film prepared by the reactive solid-phase epitaxy method. The chemical potential shift as a function of temperature was derived from the Co 3d…

Strongly Correlated Electrons · Physics 2007-10-11 Y. Ishida , H. Ohta , A. Fujimori , H. Hosono

Oxygen isotope substitution is performed in the perovskite cobalt oxide (Pr$_{0.7}$Sm$_{0.3}$)$_{0.7}$Ca$_{0.3}$CoO${_3}$ which shows a sharp spin state transition from the intermediate spin (IS) state to the low spin (LS) state at a…

Strongly Correlated Electrons · Physics 2009-11-11 G. Y. Wang , T. Wu , X. G. Luo , W. Wang , X. H. Chen

We present the results of measurements of the dc-magnetic susceptibility chi(T) and the 23Na-NMR response of Na_{0.70}CoO_{2} at temperatures between 50 and 340 K. The chi(T) data suggest that for T > 75 K, the Co ions adopt an effective…

Strongly Correlated Electrons · Physics 2009-11-10 J. L. Gavilano , D. Rau , B. Pedrini , J. Hinderer , H. R. Ott , S. M. Kazakov , J. Karpinski

We have investigated the preparation and bulk magnetic properties of NaxCoO2 in the range 0.5<x<0.95, including those for single crystals grown by the floating-zone method in an image furnace. To characterize the samples and ascertain their…

Materials Science · Physics 2007-05-23 D. Prabhakaran , A. T. Boothroyd , R. Coldea , L. M. Helme , D. A. Tennant

The resistivity and thermopower of polycrystalline (Na,Ca)Co_2O_4 were measured and analyzed. Both the quantities increase with x, suggesting that the carrier density is decreased by the substitutions of Ca^{2+} for Na^{+}. Considering that…

Strongly Correlated Electrons · Physics 2007-05-23 T. Itoh , T. Kawata , T. Kitajima , I. Terasaki

We study theoretically the electronic states in a $5d$ transition metal oxide Na$_2$IrO$_3$, in which both the spin-orbit interaction and the electron correlation play crucial roles. Tight-binding model analysis together with the…

Strongly Correlated Electrons · Physics 2009-06-25 Atsuo Shitade , Hosho Katsura , Jan Kunes , Xiao-Liang Qi , Shou-Cheng Zhang , Naoto Nagaosa

We report the first experimental evidence for a metallic phase in fluid molecular oxygen. Our electrical conductivity measurements of fluid oxygen under dynamic quasi-isentropic compression show that a non-metal/metal transition occurs at…

Condensed Matter · Physics 2007-05-23 Marina Bastea , Arthur C. Mitchell , William J. Nellis

The superconducting and structural properties of elemental strontium metal were investigated under pressures up to 60 GPa while maintaining cryogenic conditions during pressure application. Applying pressure at low temperatures reveals…

Various physical quantities are measured and analysed for the Cu-substituted thermoelectric oxide NaCo_{2-x}Cu_xO_4. As was previously known, the substituted Cu enhances the thermoelectric power, while it does not increase the resistivity…

Strongly Correlated Electrons · Physics 2009-11-07 I. Terasaki , I. Tsukada , Y. Iguchi

We studied the effect of external pressure on the optical response of the nodal-line semimetal candidate ZrSiTe by reflectivity measurements. At pressures of a few GPa, the reflectivity, optical conductivity, and loss function are strongly…

Materials Science · Physics 2019-07-24 J. Ebad-Allah , M. Krottenmüller , J. Hu , Y. L. Zhu , Z. Q. Mao , C. A. Kuntscher

Due to the dominant Kitaev exchange interactions, the cobaltate, Na$_{3}$Co$_{2}$SbO$_{6}$, has been considered to be approximate to the Kitaev quantum spin liquid (QSL). Here, we investigate both magnetic dilution and chemical pressure…

Strongly Correlated Electrons · Physics 2025-05-14 Jinou Dong , Xueqin Zhao , Lingfeng Xie , Xun Pan , Haoyuan Tang , Zhicheng Xu , Guoxiang Zhi , Chao Cao , Xiaoqun Wang , Fanlong Ning

Magnetic and transport properties of polycrystalline Gd$_{1-x}$Sr$_x$CoO$_{3}$ ($x$= 0.10-0.70) are investigated systemically. Cluster-glass magnetism for $x \leq$ 0.45 and long-range ferromagnetic order in higher doping level are observed.…

Strongly Correlated Electrons · Physics 2007-05-23 X. G. Luo , H. Li , X. H. Chen , Y. M. Xiong , G. Y. Wang , C. H. Wang , W. J. Miao , X. Li

Atomic structure and electronic band structure are fundamental properties for understanding the mechanism of superconductivity. Motivated by the discovery of pressure-induced high-temperature superconductivity at 80 K in the bilayer…

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

Superconductivity · Physics 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

We obtain the electronic states and structures of two-dimensional cobalt oxides, Na$_{x}$CoO$_{2}$ (x=0, 0.35, 0.5 and 0.75) by utilizing the full-potential linear muffin-tin orbitals (FP-LMTO) methods, from which some essential electronic…

Strongly Correlated Electrons · Physics 2009-11-10 Liang-Jian Zou , J. -L. Wang , Z. Zeng

We report on a Raman scattering study on the superconducting cobaltite $Na_xCoO_2\cdot yH_2O$ as function of Na content and hydration (x$\approx$1/3, 3/4 and y$\approx$0, 2/3, 4/3). The observed phonon scattering and scattering continua are…

Strongly Correlated Electrons · Physics 2009-11-10 P. Lemmens , V. Gnezdilov , N. N. Kovaleva , K. Y. Choi , H. Sakurai , E. Takayama-Muromachi , K. Takada , T. Sasaki , F. C. Chou , C. T. Lin , B. Keimer

The oxygen-deficient perovskite cobaltite SrCo1-xNbxO3-d was synthesized by direct solid-state reaction and its magnetotransport properties were investigated. This cobaltite exhibits an unusual ferromagnetic behavior with a transition…

Strongly Correlated Electrons · Physics 2009-11-11 T. Motohashi , V. Caignaert , V. Pralong , M. Hervieu , A. Maignan , B. Raveau

Layered Co oxide NaxCoO2.yH2O with a superconducting transition temperature Tc =4.5 K has been studied by 59Co NQR. The nuclear spin relaxation rate 1/59T1 is nearly proportional to temperature T in the normal state. In the superconducting…

Superconductivity · Physics 2009-11-10 Yoshiaki Kobayashi , Mai Yokoi , Masatoshi Sato

Broadband Dielectric Spectroscopy (BDS) measurements of P{\omicron}lyaniline/Graphene oxide composites were conducted for an as-prepared and a thermally annealed specimen, respectively, from 15K to room temperature. Electrical conductivity…