English

Spin disorder state induced by Mg$^{2+}$ doping in a Kitaev material Na$_{3}$Co$_{2}$SbO$_{6}$

Strongly Correlated Electrons 2025-05-14 v1

Abstract

Due to the dominant Kitaev exchange interactions, the cobaltate, Na3_{3}Co2_{2}SbO6_{6}, has been considered to be approximate to the Kitaev quantum spin liquid (QSL). Here, we investigate both magnetic dilution and chemical pressure effects of Na3_{3}Co2_{2}SbO6_{6} by the substitutions of Mg2+^{2+} for Co2+^{2+} through the structural, optical, magnetic and thermodynamic measurements. No structural transition has been observed, and the bandgaps remain constant in all doping levels. Combining with the magnetic and thermodynamic measurements, we find that the antiferromagnetic transition temperature is continuously suppressed with increasing Mg doping levels and completely disappears at x=0.2x=0.2. Interestingly, when the doping level xx is larger than 0.2, neither long-range magnetic order nor spin glass state has been detected, and the specific heat has a residual linear term at zero field. All features indicate that Na3_{3}(Co2x_{2-x}Mgx_{x})SbO6_{6} system enters into a novel spin disorder (NSD) state.

Keywords

Cite

@article{arxiv.2503.17948,
  title  = {Spin disorder state induced by Mg$^{2+}$ doping in a Kitaev material Na$_{3}$Co$_{2}$SbO$_{6}$},
  author = {Jinou Dong and Xueqin Zhao and Lingfeng Xie and Xun Pan and Haoyuan Tang and Zhicheng Xu and Guoxiang Zhi and Chao Cao and Xiaoqun Wang and Fanlong Ning},
  journal= {arXiv preprint arXiv:2503.17948},
  year   = {2025}
}

Comments

21 pages, 8 figures, submitted to PRB