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Transport properties of multigraphene layers on 6H-SiC substrates fabricated by thermal graphitization of SiC were studied. The principal result is that these structures were shown to contain a nearly perfect graphene layer situated between…

Materials Science · Physics 2012-12-19 A. A. Lebedev , N. V. Agrinskaya , V. A. Beresovets , V. I. Kozub , S. P. Lebedev , A. A. Sitnikova

Graphene layers were created on both C and Si faces of semi-insulating, on-axis, 4H- and 6H-SiC substrates. The process was performed under high vacuum (<10-4 mbar) in a commercial chemical vapor deposition SiC reactor. A method for H2…

Using high temperature annealing conditions with a graphite cap covering the C-face of an 8deg off-axis 4H-SiC sample, large and homogeneous single epitaxial graphene layers have been grown. Raman spectroscopy shows evidence of the almost…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 N. Camara , B. Jouault , A. Caboni , B. Jabakhanji , W. Desrat , E. Pausas , C. Consejo , N. Mestres , P. Godignon , J. Camassel

We review progress in developing epitaxial graphene as a material for carbon electronics. In particular, improvements in epitaxial graphene growth, interface control and the understanding of multilayer epitaxial graphene's electronic…

We show ~10x polariton-enhanced infrared reflectivity of epitaxial graphene on 4H-SiC, in SiC's restrahlen band (8-10um). By fitting measurements to theory, we extract the thickness, N, in monolayers (ML), momentum scattering time, Fermi…

Plasma Physics · Physics 2010-10-29 B. K. Daas , K. M. Daniels , T. S. Sudarshan , M. V. S. Chandrashekhar

Edges naturally exist in a single-layer graphene sample. Similarly, individual graphene layers in a multilayer graphene sample contribute their own edges. We study the Raman spectrum at the edge of a graphene layer laid on n layer graphene…

Materials Science · Physics 2015-01-15 Q. -Q. Li , X. Zhang , W. -P. Han , Y. Lu , W. Shi , J. -B. Wu , P. -H. Tan

The formation of graphene on the (0001) surface of SiC (the Si-face) is studied by atomic force microscopy, low-energy electron microscopy, and scanning tunneling microscopy/spectroscopy. The graphene forms due to preferential sublimation…

Materials Science · Physics 2023-05-03 Luxmi , N. Srivastava , R. M. Feenstra , P. J. Fisher

We present an investigation of large, isolated, graphene ribbons grown on the C-face of on-axis semi-insulating 6H-SiC wafers. Using a graphite cap to cover the SiC sample, we modify the desorption of the Si species during the Si…

Materials Science · Physics 2013-05-29 N. Camara , G. Rius , J-R. Huntzinger , A. Tiberj , N. Mestres , F. Perez-Murano , P. Godignon , J. Camassel

We use anhydrous ferric chloride (FeCl3) to intercalate graphite flakes consisting of 2 to 4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability and doping of the resulting intercalation compounds (ICs) are…

Materials Science · Physics 2011-06-07 W. J. Zhao , P. H. Tan , J. Liu , A. C. Ferrari

The micro-Raman scattering response of a graphene-like location on the surface of bulk natural graphite is investigated both at $T=\unit{4.2}{K}$ and at room temperature in magnetic fields up to 29 T. Two different polarization…

Mesoscale and Nanoscale Physics · Physics 2014-10-03 M. Kuhne , C. Faugeras , P. Kossacki , A. A. L. Nicolet , M. Orlita , Yu. I. Latyshev , M. Potemski

Multi-layer graphene with rhombohedral stacking is a promising carbon phase possibly displaying correlated states like magnetism or superconductivity due to the occurrence of a flat surface band at the Fermi level. Recently, flakes of…

Materials Science · Physics 2017-09-27 Abderrezak Torche , Francesco Mauri , Jean-Christophe Charlier , Matteo Calandra

An efficient route to synthesize macroscopic amounts of graphene is highly desired and a bulk characterization of such samples, in terms of the number of layers, is equally important. We present a Raman spectroscopy-based method to…

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

Materials Science · Physics 2009-11-13 D. M. Basko

Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong

In-situ high pressure Raman spectroscopy is used to study monolayer, bilayer and few-layer graphene samples supported on silicon in a diamond anvil cell to 3.5 GPa. The results show that monolayer graphene adheres to the silicon substrate…

We have investigated electron band structure of epitaxially grown graphene on an SiC(0001) substrate using angle-resolved photoemission spectroscopy. In single-layer graphene, abnormal high spectral intensity is observed at the Dirac energy…

Materials Science · Physics 2016-04-26 Jinwoong Hwang , Choongyu Hwang

We report results from two-dimensional Raman spectroscopy studies of large-area epitaxial graphene grown on SiC. Our work reveals unexpectedly large variation in Raman peak position across the sample resulting from inhomogeneity in the…

Materials Science · Physics 2015-05-13 J. A. Robinson , C. P. Puls , N. E. Staley , J. Stitt , M. A. Fanton , K. V. Emtsev , T. Seyller , Y. Liu

We demonstrate a technique to produce thin graphene layers on C-face of SiC under ultra high vacuum conditions. A stack of two SiC substrates comprising a half open cavity at the interface is used to partially confine the depleted Si atoms…

Materials Science · Physics 2013-04-23 C. Celebi , C. Yanik , A. G. Demirkol , Ismet I. Kaya

We present a computational study of the two-phonon Raman spectra of silicene and graphene within a density-functional non-orthogonal tight-binding model. Due to the presence of linear bands close to the Fermi energy in the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-04-29 Valentin N. Popov , Philippe Lambin

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard