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It is often desirable to know the controlling mechanism of survival probability of nano - or microscale particles in small cavities such as, e.g., confined submicron particles in fiber beds of high-efficiency filter media or ions/small…

Soft Condensed Matter · Physics 2023-03-29 Shubhadip Nayak , Tanwi Debnath , Shovan Das , Debajyoti Debnath , Pulak K. Ghosh

We show that when a self-avoiding polymer chain is pulled off a sticky surface by force applied to the end segment, it undergoes a first-order thermodynamic phase transition albeit without phase coexistence. This unusual feature is…

Soft Condensed Matter · Physics 2009-09-15 A. Milchev , V. G. Rostiashvili , S. Bhattacharya , T. A. Vilgis

All real physical processes, including of the first-passage time, occur with a change in entropy. This circumstance is not taken into account when studying the first-passage time, but is illustrated in this article using the example of…

Statistical Mechanics · Physics 2024-07-30 V. V. Ryazanov

This study deals with polymer looping, an important process in many chemical and biological systems. We investigate basic questions on the looping dynamics of a polymer under tension using the freely-jointed chain (FJC) model. Previous…

Statistical Mechanics · Physics 2024-10-03 Wout Laeremans , Anne Floor den Ouden , Jef Hooyberghs , Wouter G. Ellenbroek

Entropy-driven directed translocation of a flexible polymer through a cone-shaped channel is studied theoretically and using computer simulation. For a given length of the channel, the effective force of entropic origin acting on the…

Soft Condensed Matter · Physics 2015-06-12 Narges Nikoofard , Hamidreza Khalilian , Hossein Fazli

An end-grafted flexible polymer chain in 3d space between two pistons undergoes an abrupt transition from a confined coil to a flower-like conformation when the number of monomers in the chain, N, reaches a critical value. In 2d geometry,…

Statistical Mechanics · Physics 2009-11-13 Hsiao-Ping Hsu , Kurt Binder , Leonid I. Klushin , Alexander M. Skvortsov

Motivated by recent single molecule studies of proteins sliding on a DNA molecule, we explore the targeting dynamics of N particles ("proteins") sliding diffusively along a line ("DNA") in search of their target site (specific target…

Statistical Mechanics · Physics 2009-11-11 Igor M. Sokolov , Ralf Metzler , Kiran Pant , Mark C. Williams

We calculate the mean end-to-end distance ($R$) of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius $D$. A self-consistent perturbation theory is used to calculate $R$ as a function of $D$ for impenetrable…

Soft Condensed Matter · Physics 2016-08-31 G. Morrison , D. Thirumalai

We study the dynamics of flexible, semiflexible, and self-avoiding polymer chains moving under a Kramers metastable potential. Due to thermal noise, the polymers, initially placed in the metastable well, can cross the potential barrier, but…

Soft Condensed Matter · Physics 2013-12-05 Jaeoh Shin , Timo Ikonen , Mahendra D. Khandkar , Tapio Ala-Nissila , Wokyung Sung

We present here computational work on the center-of-mass displacements in thin polymer films of finite width without topological constraints and without momentum conservation obtained using a well-known lattice Monte Carlo algorithm with…

Soft Condensed Matter · Physics 2015-06-03 J. P. Wittmer , N. Schulmann , P. Polińska , J. Baschnagel

We study the propagation of tension caused by an external force along a long polymeric molecule in two different settings, namely along a free polymer in 3d space being pulled from one end, and along a pre-stretched circular polymer,…

Soft Condensed Matter · Physics 2013-06-20 Payam Rowghanian , Alexander Y. Grosberg

We extend classical Flory-Rehner theory for the expansion and compression of porous materials such as cross-linked polymer networks. The theory includes volume exclusion, affinity with the solvent, and finite stretching of the polymer…

Chemical Physics · Physics 2023-09-28 P. M. Biesheuvel , H. Fan , M. Elimelech

In last passage percolation models lying in the KPZ universality class, long maximizing paths have a typical deviation from the linear interpolation of their endpoints governed by the two-thirds power of the interpolating distance. This…

Probability · Mathematics 2019-09-18 Alan Hammond

We computationally investigate the active transport of tangentially-driven polymers with varying degrees of flexibility and activity in two-dimensional square lattices of obstacles. Tight periodic confinement induces notable conformational…

Soft Condensed Matter · Physics 2023-10-04 Mohammad Fazelzadeh , Ehsan Irani , Zahra Mokhtari , Sara Jabbari-Farouji

The purpose of this paper is to investigate several analytical methods of solving first passage (FP) problem for the Rouse model, a simplest model of a polymer chain. We show that this problem has to be treated as a multi-dimensional…

Soft Condensed Matter · Physics 2015-12-09 Jing Cao , Jian Zhu , Zuowei Wang , Alexei E. Likhtman

We calculate the first passage time distribution for diffusion through a cylindrical pore with sticky walls. A particle diffusively explores the interior of the pore through a series of binding and unbinding events with the cylinder wall.…

Soft Condensed Matter · Physics 2009-09-30 Nicholas A. Licata , Stephan W. Grill

The nematic ordering in semiflexible polymers with contour length $L$ exceeding their persistence length $\ell_p$ is described by a confinement of the polymers in a cylinder of radius $r_{eff}$ much larger than the radius $r_\rho$, expected…

Soft Condensed Matter · Physics 2016-05-11 Sergei A. Egorov , Andrey Milchev , Kurt Binder

The distribution of the first-passage time (FPT)$T_a$ for a Brownian particle with drift $\mu$ subject to hitting an absorber at a level $a>0$ is well-known and given by its density $\gamma(t) = \frac{a}{\sqrt{2 \pi t^3} } e^{-\frac{(a-\mu…

Statistical Mechanics · Physics 2024-09-04 Alain Mazzolo

By quantitative studies of statistics of polymer stretching in a random flow and of a flow field we demonstrate that the stretching of polymer molecules in a 3D random flow occurs rather sharply via the coil-stretch transition at the value…

Chaotic Dynamics · Physics 2009-11-10 S. Gerashchenko , C. Chevallard , V. Steinberg

We measure hole transport in poly(3-hexylthiophene) field effect transistors with channel lengths from 3 $\mu$m down to 200 nm, from room temperature down to 10 K. Near room temperature effective mobilities inferred from linear regime…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 B. H. Hamadani , D. Natelson
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