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Theory of long-range interactions between an atom in its ground S state and a linear molecule in a degenerate state with a non-zero projection of the electronic orbital angular momentum is presented. It is shown how the long-range…

Chemical Physics · Physics 2015-05-20 Wojciech Skomorowski , Robert Moszynski

We revisit the derivation of multipole contributions to the atom-wall interaction previously presented in [G. Lach et al., Phys. Rev. A 81, 052507 (2010)]. A careful reconsideration of the angular-momentum decomposition of the second-,…

Atomic Physics · Physics 2024-01-12 Ulrich D. Jentschura

We present semiempirical calculations of long-range van der Waals interactions for two interacting metastable rare-gas atoms Ne through Xe. Dispersion coefficients $C_6$ are obtained for homonuclear molecular potentials asymptotically…

Atomic Physics · Physics 2009-11-06 A. Derevianko , A. Dalgarno

We present time-resolved spectroscopic measurements of Rydberg-Rydberg interactions in an ultracold gas, revealing the pair dynamics induced by long-range van der Waals interactions between the atoms. By detuning the excitation laser, a…

Atomic Physics · Physics 2015-06-26 T. Amthor , M. Reetz-Lamour , S. Westermann , J. Denskat , M. Weidemüller

The long-range forces that act between three atoms are analysed in both atom-diatom and atom-atom-atom representations. Expressions for atom-diatom dispersion coefficients are obtained in terms of 3-body nonadditive coefficients. The…

Atomic and Molecular Clusters · Physics 2009-11-11 Marko T. Cvitas , Pavel Soldan , Jeremy M. Hutson

Van der Waals interactions are interactions between dipoles. Similarly, quadrupole-quadrupole interactions are interactions between quadrupoles. In this article, we focus on the interactions between two dipoles or two quadrupoles.…

Atomic and Molecular Clusters · Physics 2022-07-18 Jianing Han , Juliet Michell , Morgan Umstead

The long-range interaction of excited neutral atoms has a number of interesting and surprising properties, such as the prevalence of long-range, oscillatory tails, and the emergence of numerically large can der Waals C_6 coefficients.…

Atomic Physics · Physics 2017-09-25 C. M. Adhikari , V. Debierre , U. D. Jentschura

The problem of long-range correlations of particles produced in high- energy collisions is discussed. Long-range correlations involve large groups of particles. Among them are, e.g., those correlations which lead to ring-like and elliptic…

High Energy Physics - Phenomenology · Physics 2016-09-06 I. M. Dremin

In a recent work [Phys. Rev. Lett. 98, 023004 (2007)] we have investigated the influence of attractive van der Waals interaction on the pair distribution and Penning ionization dynamics of ultracold Rydberg gases. Here we extend this…

Atomic Physics · Physics 2009-11-13 Thomas Amthor , Markus Reetz-Lamour , Christian Giese , Matthias Weidemüller

We computed the long-range interactions between two identical polar bialkali molecules in their rovibronic ground level, for all ten species involving Li, Na, K, Rb and Cs, using accurate quantum chemistry results combined with available…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Romain Vexiau , Mireille Aymar , Nadia Bouloufa-Maafa , Olivier Dulieu

The long-range interactions of two atoms, of an atom and a dielectric wall, of an atom and a perfectly conducting wall, and of an atom between two perfectly conducting walls are calculated, including the effects of retardation, for Li using…

Atomic Physics · Physics 2008-02-03 Zong-Chao Yan , A. Dalgarno , J. F. Babb

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

The isotropic and anisotropic coefficients $C^{l,m}_n$ of the long-range spherical expansion $\sim 1/R^n$ ($R$ -- the intermolecular distance) of the dispersion and inductions intermolecular energies are calculated using the first…

Chemical Physics · Physics 2023-04-04 Leonid Shirkov , Michał Tomza

The long-range part of the interatomic interactions plays a substantial role in the collisional dynamics of ultracold gases. Here, we report on the calculation of the isotropic and anisotropic $C_6$ coefficients characterizing the van der…

Atomic Physics · Physics 2024-01-24 Klaudia Zaremba-Kopczyk , Michał Tomza , Maxence Lepers

The ground state and excited state resonance dipole-dipole interaction energy between two elongated conducting molecules are explored. We review the current status for ground state interactions. This interaction is found to be of a much…

Chemical Physics · Physics 2025-11-03 Subhojit Pal , Iver Brevik , Mathias Boström

Polarizabilities, dispersion coefficients, and long-range atom-surface interaction potentials are calculated for the n=2 triplet and singlet states of helium using highly accurate, variationally determined, wave functions.

Atomic Physics · Physics 2007-05-23 Zong-Chao Yan , J. F. Babb

In this study, we reexamine the long-range interaction between two atoms placed in an equilibrium thermal radiation environment. Employing the formalism of quantum electrodynamics at finite temperatures, we derive an expression for the…

Atomic Physics · Physics 2023-12-19 T. Zalialiutdinov , D. Solovyev

The atomic dipole polarizability, $\alpha$, and the van der Waals (vdW) radius, $R_{\rm vdW}$, are two key quantities to describe vdW interactions between atoms in molecules and materials. Until now, they have been determined independently…

Chemical Physics · Physics 2018-11-07 Dmitry V. Fedorov , Mainak Sadhukhan , Martin Stöhr , Alexandre Tkatchenko

We consider the scattering of two color dipoles (e.g., heavy quarkonium states) at low energy - a QCD analog of Van der Waals interaction. Even though the couplings of the dipoles to the gluon field can be described in perturbation theory,…

High Energy Physics - Phenomenology · Physics 2009-10-31 H. Fujii , D. Kharzeev

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann