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Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

Neutral atoms interact through a van der Waals potential which asymptotically falls off as r^{-6}. In ultracold gases, this interaction can be described to a good approximation by the atom-atom scattering length. However, corrections arise…

Other Condensed Matter · Physics 2009-11-13 Ryan M. Kalas , D. Blume

We report a new technique to determine the van der Waals coeffcients of lithium (Li) atoms based on the relativistic coupled-cluster theory. These quantities are determined using the imaginary parts of the scalar dipole and quadrupole…

Atomic Physics · Physics 2009-11-13 L. W. Wansbeek , B. K. Sahoo , R. G. E. Timmermans , B. P. Das , D. Mukherjee

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

The van der Waals potential of two atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is studied. Starting from a polarizable atom placed within a given geometry, its interaction with a…

Quantum Physics · Physics 2007-09-11 Stefan Yoshi Buhmann , Hassan Safari , Ho Trung Dung , Dirk-Gunnar Welsch

The first three dynamic multipole polarizabilities for the ground state of hydrogen, helium, hydride ion, and positronium hydride PsH have been computed using the variational Monte Carlo (VMC) method and explicitly correlated wave…

Atomic Physics · Physics 2009-11-06 Massimo Mella , Dario Bressanini , Gabriele Morosi

The random-phase approximation with exchange (RPAE) is used with a $B$-spline basis to compute dynamic dipole polarizabilities of noble-gas atoms and several other closed-shell atoms (Be, Mg, Ca, Zn, Sr, Cd, and Ba). From these, values of…

Atomic Physics · Physics 2015-07-08 A. R. Swann , J. A. Ludlow , G. F. Gribakin

A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…

Materials Science · Physics 2009-04-20 Huy-Viet Nguyen , Stefano de Gironcoli

Since general relativity is a consistent low energy effective field theory, it is possible to compute quantum corrections to classical forces. Here we compute a quantum correction to the gravitational potential between a pair of polarizable…

High Energy Physics - Theory · Physics 2016-07-20 L. H. Ford , Mark P. Hertzberg , J. Karouby

The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

Atomic Physics · Physics 2024-05-16 Etienne F. Walraven , Tijs Karman

Van der Waals interactions are ubiquitous and they play an important role for the stability of materials. Current understanding of this type of coupling is based on linear response theory, while optical nonlinearities are rarely considered…

Materials Science · Physics 2024-08-27 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

We investigate the resonance quadrupole-quadrupole interaction between two entangled gravitationally polarizable objects induced by a bath of fluctuating quantum gravitational fields in vacuum in the framework of linearized quantum gravity.…

General Relativity and Quantum Cosmology · Physics 2020-09-08 Yongshun Hu , Jiawei Hu , Hongwei Yu , Puxun Wu

The interaction of an electron with a local static charge distribution (e.g., an atom or molecule) is dominated at large distances by the radial 1/r Coulomb potential. The second order effect comes from the non-central electric dipole…

Quantum Physics · Physics 2023-02-08 A. D. Alhaidari , H. Bahlouli

We estimate polarizabilities of atoms in molecules without electron density, using a Voronoi tesselation approach instead of conventional density partitioning schemes. The resulting atomic dispersion coefficients are calculated, as well as…

Chemical Physics · Physics 2015-08-31 Tristan Bereau , O. Anatole von Lilienfeld

Coherently manipulating Rydberg atoms in mesoscopic systems has proven challenging due to the unwanted population of nearby Rydberg levels by black-body radiation. Recently, there have been some efforts towards understanding these effects…

The van der Waals coefficients, from C_11 through to C_16 resulting from 2nd, 3rd and 4th order perturbation theory are estimated for the alkali (Li, Na, K and Rb) atoms. The dispersion coefficients are also computed for all possible…

Atomic Physics · Physics 2007-05-23 J. Mitroy , M. W. J. Bromley

We compute the interaction energies of a two-atom system placed in the middle of a perfectly reflecting planar cavity, in the perturbative regime. Explicit expressions are provided for the van der Waals potentials of two polarisable atomic…

Quantum Physics · Physics 2017-11-01 M. Donaire , J. M. Muñoz-Castañeda , L. M. Nieto

Dynamical and thermal characterizations of excited nuclear systems produced during the collisions between two heavy ions at intermediate incident energies are presented by means of a review of experimental and theoretical work performed in…

Nuclear Experiment · Physics 2009-11-11 G. Verde , A. Chbihi , R. Ghetti , J. Helgesson

Optical double-quantum two-dimensional coherent spectroscopy (2DCS) was implemented to probe interatomic dipole-dipole interactions in both potassium and rubidium atomic vapors. The dipole-dipole interaction was detected at densities of…

Atomic Physics · Physics 2019-09-26 Shaogang Yu , Michael Titze , Yifu Zhu , Xiaojun Liu , Hebin Li

Long- and short-range correlations for pairs of charged particles are studied via two-particle angular correlations in pp collisions at $\sqrt{s}=13$ TeV and p$-$Pb collisions at $\sqrt{s_\mathrm{NN}} = 5.02$ TeV. The correlation functions…

Nuclear Experiment · Physics 2024-04-15 ALICE Collaboration