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Dispersion Interaction Between Thin Conducting Cylinders

Chemical Physics 2025-11-03 v2 Other Condensed Matter

Abstract

The ground state and excited state resonance dipole-dipole interaction energy between two elongated conducting molecules are explored. We review the current status for ground state interactions. This interaction is found to be of a much longer range than in the case when the molecules are pointlike and nonconducting. These are well known results found earlier by Davies, Ninham, and Richmond, and later, using a different formalism, by Rubio and co-workers. We show how the theory can be extended to excited state interactions. A characteristic property following from our calculation is that the interaction energy dependence with separation (RR) goes like f(R)/R2f(R)/R^2 both for resonance and for the van der Waals case in the long range limit. In some limits f(R)f(R) has a logarithmic dependency and in others it takes constant values. We predict an unusual slow decay rate for the energy transfer between conducting molecules.

Keywords

Cite

@article{arxiv.2406.08047,
  title  = {Dispersion Interaction Between Thin Conducting Cylinders},
  author = {Subhojit Pal and Iver Brevik and Mathias Boström},
  journal= {arXiv preprint arXiv:2406.08047},
  year   = {2025}
}
R2 v1 2026-06-28T17:02:51.783Z