Dispersion Interaction Between Thin Conducting Cylinders
Abstract
The ground state and excited state resonance dipole-dipole interaction energy between two elongated conducting molecules are explored. We review the current status for ground state interactions. This interaction is found to be of a much longer range than in the case when the molecules are pointlike and nonconducting. These are well known results found earlier by Davies, Ninham, and Richmond, and later, using a different formalism, by Rubio and co-workers. We show how the theory can be extended to excited state interactions. A characteristic property following from our calculation is that the interaction energy dependence with separation () goes like both for resonance and for the van der Waals case in the long range limit. In some limits has a logarithmic dependency and in others it takes constant values. We predict an unusual slow decay rate for the energy transfer between conducting molecules.
Cite
@article{arxiv.2406.08047,
title = {Dispersion Interaction Between Thin Conducting Cylinders},
author = {Subhojit Pal and Iver Brevik and Mathias Boström},
journal= {arXiv preprint arXiv:2406.08047},
year = {2025}
}