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The long-range electrostatic interactions between molecules depend strongly on their relative orientation, which manifests as a rotational state dependence. Interactions between molecules in the same rotational quantum state are well-known…

Atomic Physics · Physics 2024-05-16 Etienne F. Walraven , Tijs Karman

A quantum electrodynamic calculation of the interaction of an excited-state atom with a ground-state atom is performed. For an excited reference state and a lower-lying virtual state, the contribution to the interaction energy naturally…

Quantum Physics · Physics 2017-05-19 U. D. Jentschura , V. Debierre

Theory of long-range interactions between an atom in its ground S state and a linear molecule in a degenerate state with a non-zero projection of the electronic orbital angular momentum is presented. It is shown how the long-range…

Chemical Physics · Physics 2015-05-20 Wojciech Skomorowski , Robert Moszynski

Using a recently obtained (general) formula for the interaction energy between an excited and a ground-state atom (Sherkunov Y 2007 Phys. Rev. A 75 012705), we consider the interaction energy between two such atoms near the interface…

Quantum Physics · Physics 2008-04-10 Marin-Slobodan Tomas

The Casimir-Polder potential for interaction between an excited atom and a ground-state one in the retarded case obtained with the help of perturbation technique drops as R^-2 with the distance between the atoms [E.A. Power,…

Quantum Physics · Physics 2007-05-23 Yury Sherkunov

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

An expression for the conductance of interacting electrons in the diffusive regime as a function of the ensemble averaged persistent current and the compressibility of the system is presented. This expression involves only ground-state…

Condensed Matter · Physics 2009-10-28 Richard Berkovits , Yshai Avishai

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

The effects of ground-state correlations on the dipole and quadrupole excitations are studied for $^{40}$Ca and $^{48}$Ca using the extended random phase approximation (ERPA) derived from the time-dependent density-matrix theory. Large…

Nuclear Theory · Physics 2017-12-07 Mitsuru Tohyama

We study the shift of rotational levels of a diatomic polar molecule due to its van der Waals (vdW) interaction with a gently curved dielectric surface at temperature $T$, and submicron separations. The molecule is assumed to be in its…

Quantum Physics · Physics 2016-08-18 Giuseppe Bimonte , Thorsten Emig , Robert L. Jaffe , Mehran Kardar

We report on a quantum electrodynamic (QED) investigation of the interaction between a ground state atom with another atom in an excited state. General expressions, applicable to any atom, are indicated for the long-range tails which are…

Quantum Physics · Physics 2017-04-27 U. D. Jentschura , C. M. Adhikari , V. Debierre

Molecular excited vibrational states are metastable states and we incorporate their finite lifetimes into the theory of vibrational energy transfer between weakly interacting molecules, i.e., at internuclear distances at which they do not…

Chemical Physics · Physics 2019-07-24 Lorenz S. Cederbaum

The theory of the long-range interaction of metastable excited atomic states with ground-state atoms is analyzed. We show that the long-range interaction is essentially modified when quasi-degenerate states are available for virtual…

Atomic Physics · Physics 2017-02-15 C. M. Adhikari , V. Debierre , A. Matveev , N. Kolachevsky , U. D. Jentschura

We show the existence of ultra-long-range giant dipole molecules formed by a neutral alkali ground state atom that is bound to the decentered electronic wave function of a giant dipole atom. The adiabatic potential surfaces emerging from…

Atomic Physics · Physics 2012-03-14 Markus Kurz , Michael Mayle , Peter Schmelcher

The van der Waals interaction between two ground-state atoms is calculated for two electrically or magnetically polarizable particles embedded in a dispersive magneto-dielectric medium. Unlike previous calculations which infer the atom-atom…

Quantum Physics · Physics 2009-11-13 S. Spagnolo , D. A. R. Dalvit , P. W. Milonni

The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals…

Atomic Physics · Physics 2015-05-06 Hasi Ray , Anuradha De , Deparpita Ray

The issue of retarded long-range resonant interactions between two molecules with oscillating dipole moments is reinvestigated within the framework of classical electrodynamics. By taking advantage of a theorem in complex analysis, we…

Biological Physics · Physics 2012-01-26 Jordane Preto , Marco Pettini

Coherently manipulating Rydberg atoms in mesoscopic systems has proven challenging due to the unwanted population of nearby Rydberg levels by black-body radiation. Recently, there have been some efforts towards understanding these effects…

Using the multipolar expansion of electrostatic and magnetostatic potential energies, we characterize the long-range interactions between two weakly-bound diatomic molecules, taking as an example the paramagnetic Er$_2$ Feshbach molecules…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Goulven Quéméner , Eliane Luc-Koenig , Olivier Dulieu
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