Related papers: Hydrocarbon anions in interstellar clouds and circ…
The formation of Polycyclic Aromatic Hydrocarbons in the circumstellar outflows of evolved stars is reviewed, with an emphasis on carbon stars on the Asymptotic Giant Branch. Evidence for PAHs present in their winds is provided by…
We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of…
We present recent observations of small hydrocarbons (C3H2, C2H, C4H) with high abundances in the Photo-Dissociation Region of the Horsehead nebula. Our results show for the first time observational indications that the small hydrocarbon…
The cosmological origin of carbon, the fourth most abundant element in the Universe, is not well known and matter of heavy debate. We investigate the behavior of C/O to O/H in order to constrain the production mechanism of carbon. We…
The reactions of carbon atoms with dihydrogen have been investigated in liquid helium droplets at $T$ = 0.37 K. A calorimetric technique was applied to monitor the energy released in the reaction. The barrierless reaction between a single…
The study of cyclic hydrocarbons is of utmost relevance in current astrochemical research, as they are considered to be among the most significant reservoirs of carbon in the interstellar medium. However, while unsaturated cyclic…
Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation…
We report the detection, for the first time in space, of a new non-functionalised hydrocarbon cycle in the direction of TMC-1: o-C6H4 (ortho-benzyne). We derive a column density for this hydrocarbon cycle of (5 +/- 1)e11 cm-2. The abundance…
The laboratory detection of previously unobserved resonance-stabilized C$_9$H$_5$ and C$_9$H$_9$ radicals in the supersonic expansion of a hydrocarbon discharge source is reported. The radicals are tentatively assigned as…
It is long debated if pre-biotic molecules are indeed present in the interstellar medium. Despite substantial works pointing to their existence, pre-biotic molecules are yet to be discovered with a complete confidence. In this paper, our…
We present the detection of C4H2 for first time in the envelope of the C-rich AGB star IRC+10216 based on high spectral resolution mid-IR observations carried out with the Texas Echelon-cross-Echelle Spectrograph (TEXES) mounted on the…
We report the first detection of HC$_{5}$$^{15}$N with the $J=9-8$ rotational line from the cyanopolyyne peak in Taurus Molecular Cloud-1 (TMC-1 CP) using the 45-m radio telescope of the Nobeyama Radio Observatory. The column density of…
We report the detection of large hydrocarbon cycles toward several cold dense clouds. We observed four sources (L1495B, Lupus-1A, L483, and L1527) in the Q band (31-50 GHz) using the Yebes 40m radiotelescope. Using the line stack technique,…
We report on the detection with the Infrared Space Observatory (ISO) of a molecular band at 57.5 microns (174 cm^{-1}) in carbon-rich evolved stars and in Sgr B2. Taking into account the chemistry of these objects the most likelihood…
We report the detection of the elusive carbon-chain radical C5N in the dark cloud TMC1 and its tentative detection in the circumstellar envelope IRC+10216. C5N appears to be two orders of magnitude less abundant than the related molecule…
Context: The presence of water in the wind of the extreme carbon star IRC+10216 has been confirmed by the Herschel telescope. The regions where the high-J H2O lines have been detected are close to the star at radii r \geq 15 R\ast. Aims: We…
Hydrocarbons are ubiquitous in the interstellar medium, but their formation is still not well understood, depending on the physical environment they are found in. M8 is host to one of the brightest HII regions and PDRs in our galaxy. Using…
This paper presents an analysis of the concentration of the hydrogen molecule inside the ionized region of planetary nebulae. The equations corresponding to the ionization and chemical equilibria of H, H+, H-, H2, H2+, and H3+ are coupled…
A model of a mixed helium-hydrogenic atmosphere of the isolated neutron star 1E1207.4-5209 is proposed. It is based on the assumption that the main components in the atmosphere are the exotic molecular ions $He_2^{3+}$ and $H_3^{2+}$ with…
We report the first identification in space of H2NC, a high-energy isomer of H2CN that has been largely ignored in chemical and astrochemical studies. The observation of various unidentified lines around 72.2 GHz in the cold dark cloud L483…