Related papers: Hydrocarbon anions in interstellar clouds and circ…

We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several…

We report the detection of emission in the J=1-0 rotational transition of hydrogen fluoride (HF), together with observations of the J=1-0 to J=3-2 rotational lines of H35Cl and H37Cl, towards the envelope of the carbon star IRC +10216.…

Ubiquitously found in the Universe, atomic hydrogen represents up to 70% of the neutral gas composition of the Milky Way. As an adatom, hydrogen can physisorb or chemisorb onto interstellar dust grains and icy mantles, thereby contributing…

Asymptotic giant branch (AGB)stars create a rich inventory of molecules in their envelopes as they lose mass during later stages of their evolution. These molecules cannot survive the conditions in interstellar space, where they are exposed…

We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques.…

Recent spectroscopic observations of intermediate- and high-velocity clouds (IVCs and HVCs) in the Milky Way halo have unveiled the presence of diffuse interstellar molecular hydrogen (H_2) several kpc away from the Galactic disk. Most of…

Linear C4H and cyclic c-C3H2, as small unsaturated hydrocarbons, are the key precursors to complex organic molecules and are critical components of the interstellar medium. We present on-the-fly mapping observations of C4H 9-8 lines, c-C3H2…

Carbon chain molecules may be an important reservoir of reactive organics during star and planet formation. Carbon chains have been observed toward several low-mass young stellar objects (YSOs), but their typical abundances and chemical…

We consider the possibility that solid molecular hydrogen is present in interstellar space. If so cosmic-rays and energetic photons cause ionisation in the solid leading to the formation of H6+. This ion is not produced by gas-phase…

Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…

This paper is the third in a series reporting on a study of carbon abundances in a carefully chosen sample of planetary nebulae representing a large range in progenitor mass and metallicity. We make use of the IUE Final Archive database…

In order to find out capable chemical evolution step from astronomically created organic in interstellar space to biological organic on the earth, infrared spectrum of nitrogen substituted carbon pentagon-hexagon coupled polycyclic aromatic…

We present the theory of radiative association of atoms and molecules, and we apply it to the (H$_2$-H$^-$) van der Waals complex. We discuss the possibility for the H$_3^-$ ion to be formed in the interstellar medium in an environment with…

Molecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The…

We report the first detection of the reactive ions CO+ and HOC+ towards ultracompact (UC) HII regions, particularly in Mon R2 and G29.96-0.02. We have observed two positions in Mon R2, namely the peak of the UC HII region and a position in…

We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core,…

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…

We use the absorption features from neutral argon at 1048 and 1066 A to determine interstellar abundances or their lower limits toward nine early-type stars. These features were observed with the Interstellar Medium Absorption Profile…

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

In recent years, many questions have arisen regarding the chemistry of photochemical products in the carbon-rich winds of evolved stars. To address them, it is imperative to constrain the distributions of such species through high angular…