English

Formation of the simplest stable negative molecular ion H3- in interstellar medium

Atomic Physics 2009-10-14 v1 Plasma Physics

Abstract

We present the theory of radiative association of atoms and molecules, and we apply it to the (H2_2-H^-) van der Waals complex. We discuss the possibility for the H3_3^- ion to be formed in the interstellar medium in an environment with abundant ionized molecular hydrogen H2+_2^+. The observation of H3_3^- would also be a probe for the presence of H^- in the interstellar medium. By computing the electronic structure of the H3_3^- ion, we determine its dipole moment, bound states, rotational constants, predissociated vibrational resonances and their lifetimes, and suggest a way to detect the ion in the interstellar medium.

Keywords

Cite

@article{arxiv.0910.2330,
  title  = {Formation of the simplest stable negative molecular ion H3- in interstellar medium},
  author = {V. Kokoouline and M. Ayouz and R. Guerout and M. Raoult and J. Robert and O. Dulieu},
  journal= {arXiv preprint arXiv:0910.2330},
  year   = {2009}
}