Related papers: Hydrocarbon anions in interstellar clouds and circ…
The Green Bank Telescope H II Region Discovery Survey (GBT HRDS) found hundreds of previously unknown Galactic regions of massive star formation by detecting hydrogen radio recombination line (RRL) emission from candidate H II region…
Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong…
Molecules harbouring sulfur are thought to have played a key role in the biological processes of life on Earth, and thus, they are of much interest when found in space. Here we report on the astronomical detection of a six-membered…
Stellar and nebular abundance indicators reveal that there exists significant abundance fluctuations in the interstellar medium (ISM) of gas-rich galaxies. It is shown that at the present observed solar level of O/H $\sim 6 \times 10^{-4}$,…
A new molecular hydrogen cloud is found in the sub-damped Ly-alpha absorber [log N(HI)=19.88+/-0.05] at the redshift z=1.15 toward the bright quasar HE0515-4414 (zem = 1.71). More than 30 absorption features in the Lyman band system of H2…
We present the study of CI/H$_2$ relative abundance in the diffuse cold neutral medium. Using the chemical and thermal balance model we calculated the dependence of CI/H$_2$ on the main parameters of the medium: hydrogen number density,…
Nitrogen oxides are thought to play a significant role as a nitrogen reservoir and to potentially participate in the formation of more complex species. Until now, only NO, N$_2$O and HNO have been detected in the interstellar medium. We…
We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement…
We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen within diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photo-…
New interferometric observations of SiO J=5-4 circumstellar line emission around the carbon star IRC+10216, using the Submillimeter Array, are presented. Complemented by multi-transition single-dish observations, including infrared…
Small hydrocarbons, such as C2H, C3H and C3H2 are more abundant in photo-dissociation regions (PDRs) than expected based on gas-phase chemical models. To explore the hydrocarbon chemistry further, we observed a key intermediate species, the…
We have obtained deep HI observations in the direction of 22 continuum sources without previously detected cold neutral medium (CNM). 18 CNM clouds were detected with the typical HI column density of $3\times10^{18}$ cm$^{-2}$. Our…
Hydrogen atom tunneling likely plays a substantial role in the gas-phase chemistry of astrochemical environments. To determine the potential effect that it has on the chemical modeling of aromatic molecules, we screened the kida.uva.2024…
It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…
In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction…
The Voyager 1 flyby of Titan in 1980 gave a first glimpse of the chemical complexity of Titan's atmosphere, detecting many new molecules with the infrared spectrometer (IRIS). These included propane (C3H8) and propyne (CH3C2H), while the…
A mechanism based on the penetration of interstellar ultraviolet photons into the inner layers of clumpy circumstellar envelopes around AGB stars is proposed to explain the non-equilibrium chemistry observed in such objects. We show through…
Context: Molecular hydrogen (H2) is the most abundant molecule in the circumstellar (CS) environments of young stars, and is a key element in giant planet formation. The measurement of the H2 content provides the most direct probe of the…
Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds, which are near the beginning of the star formation cycle.…
Molecular hydrogen (H2) is the primary component of the reservoirs of cold, dense gas that fuel star formation in our galaxy. While the H2 abundance is ultimately regulated by physical processes operating on small scales in the interstellar…