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Herein we report experimental evidence of directional SERS from molecules situated inside a single nanowire-nanoparticle junction cavity. The emission was confined to a narrow range of wavevectors perpendicular to the axis of the cavity. In…

Single molecule detection, sequencing and conformational mapping of aptamers are important for improving medical and biosensing technologies and for better understanding of biological processes at the molecular level. We obtain vibrational…

Biomolecules · Quantitative Biology 2016-12-05 Siyu He , Hongyuan Li , Zhe He , Dmitri V. Voronine

Undoubtedly, Raman spectroscopy is one of the most elaborated spectroscopy tools in materials science, chemistry, medicine and optics. However, when it comes to the analysis of nanostructured specimens, accessing the Raman spectra resulting…

Engineered electromagnetic fields in plasmonic nanopores enable enhanced optical detection and their use in single molecule sequencing. Here, a plasmonic nanopore prepared in a thick nanoporous film is used to investigate the interaction…

Metal nanostructures have received significant attention in recent years owing to their peculiar physical and chemical properties, which span a wide range of practical applications in a variety of scientific and engineering fields. Herein,…

Tip-enhanced Raman spectroscopy (TERS) is a valuable method for surface analysis with nanometer to angstrom-scale resolution, however, the accurate simulation of particular TERS signals remains a computational challenge. We present a unique…

Surface-enhanced Raman spectroscopy (SERS) demands reliable, high enhancement substrates in order to be used in different fields of application. Here, we introduce freestanding porous gold membranes (PAuM) as easy to produce, scalable,…

Today's cutting-edge optical spectroscopic exploratory tools, such as Raman or infrared spectroscopy, rely on methods of signal enhancement as a route for their development. These methods are indispensable for substance identification and…

A mechanism for additional enhancement of SERS in the nanoparticle-on-mirror scheme is proposed. This new mechanism is based on the use of a substrate made of material with a near-minus-one permittivity. The setup involves a plasmonic…

Optics · Physics 2026-05-11 Alexey P. Vinogradov , Evgeny S. Andrianov

This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…

Chemical Physics · Physics 2008-04-01 Catalin C. Neacsu , Samuel Berweger , Markus B. Raschke

Trisoctahedral (TOH) shaped Au nanocrystals (NCs) have emerged as a new class of metal nanoparticles (MNP) due to its superior catalystic and SERS activities caused by the presence of high density atomic steps and dangling bonds on their…

Materials Science · Physics 2017-05-15 Achyut Maity , Arpan Maiti , Biswarup Satpati , Avinash Patsha , Sandip Dhara , Tapas Kumar Chini

The programmable assembly of DNA strands is a promising tool for building tailored bottom-up nanostructures. Here, we present a plasmonic nanosystem obtained by the base-pairing mediated aggregation of gold nanoparticles (NPs) which are…

Applied Physics · Physics 2019-12-03 D. Caprara , F. Ripanti , A. Capocefalo , A. Sarra , F. Brasili , C. Petrillo , C. Fasolato , P. Postorino

In analogy to cavity optomechanics, enhancing specific sidebands of a Raman process with narrowband optical resonators would allow for parametric amplification, entanglement of light and molecular vibrations, and reduced transduction noise.…

Optics · Physics 2023-01-09 Ilan Shlesinger , Isabelle M. Palstra , A. Femius Koenderink

Achieving reliable and quantifiable performance in large-area surface-enhanced Raman spectroscopy (SERS) substrates has long been a formidable challenge. It requires substantial signal enhancement while maintaining a reproducible and…

Resonant dielectric nanoparticles (RDNs) made of materials with large positive dielectric permittivity, such as Si, GaP, GaAs, have become a powerful platform for modern light science, enabling various fascinating applications in…

Optics · Physics 2017-10-30 Alex Krasnok , Martin Caldarola , Nicolas Bonod , Andrea Alú

We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , P. G. Etchegoin

Ordered Ag nanowire arrays with high aspect ratio and high density self-supporting Ag nanowire patterns were successfully prepared using potentiostatic electrodeposition within the confined nanochannels of a commercial porous anodic…

Materials Science · Physics 2011-06-15 Baoliang Sun , Xiaohong Jiang , Shuxi Dai , Zuliang Du

New type of plasmonic nanoparticles - silver octopods that can be synthesized with a variety of shapes - have been demonstrated to show versatile optical response using the discrete dipole approximation. The octopods show a complex behavior…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Ivan I. Naumov , Zhiyong Li , Alexander M. Bratkovsky

Coherent spin resonance methods such as nuclear magnetic resonance (NMR) and electron spin resonance (ESR) spectroscopy have led to spectrally highly sensitive, non-invasive quantum imaging techniques with groundbreaking applications in…

Waveguide-enhanced Raman spectroscopy (WERS) is a promising technique for sensitive and selective detection of chemicals in a compact chip-scale platform. Coupling light on and off the sensor chip with fibers however presents challenges…

Applied Physics · Physics 2020-05-05 Derek M. Kita , Jérôme Michon , Juejun Hu
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